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Solid-State displacement reactions between selected metals and sulfides

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Abstract

Displacement reactions between sulfides and metals in the solid state are studied and compared with the resultant morphologies previously observed in oxide-metal displacement reactions. Sufficient thermodynamic and diffusion data were available only for the theoretical prediction of product morphology for the Fe-Ni3S2 reaction couple. Experiments substantiated the theoretical prediction of an aggregate morphology for this couple at 600°C. The growth of the product zone for the Fe-Ni3S2 reaction couple obeyed parabolic kinetics. The experimentally observed morphologies for Co-Ni3S2, Fe-Co4S3, Mn-Crs, Nb-Cu.2S, Cr-Cu2S, Cr-Ni3S2, and Mn-Cu2S reaction couples are also reported and rationalized.

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Authors and Affiliations

  1. Rensselaer Polytechnic Institute, 12181, Troy, New York

    S. R. Shatynski (Assistant Professor of Materials Engineering)

  2. Ohio State University, 43210, Columbus, OH

    J. P. Hirth (Professor of Mettalurgical Engineering) & R. A. Rapp (Professor of Mettalurgical Engineering)

Authors
  1. S. R. Shatynski
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  2. J. P. Hirth
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  3. R. A. Rapp
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Shatynski, S.R., Hirth, J.P. & Rapp, R.A. Solid-State displacement reactions between selected metals and sulfides. Metall Trans A 10, 591–598 (1979). https://doi.org/10.1007/BF02658322

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  • DOI: https://doi.org/10.1007/BF02658322

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