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The reaction of hf with polyacetylene

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Abstract

Anhydrous HF reacts with polyacetylene to produce a material with high conductivity. Infrared spectra of lightly doped samples show bands characteristic of a delocalized positive charge along the polymer chain. Upon heavier doping, conductivities of 1⫁−10 (ohm-cm)−1 are measured. Addition of ammonia produces an ammonium ion on the chain, and destroys the conductivity of the material. A discussion of the doping mechanism and related reactions is given.

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Authors and Affiliations

  1. IBM Research Laboratory, 5600 Cottle Road, 95193, San Jose, California

    B. McQuillan, G. B. Street & T. C. Clarke

Authors
  1. B. McQuillan
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  2. G. B. Street
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  3. T. C. Clarke
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McQuillan, B., Street, G.B. & Clarke, T.C. The reaction of hf with polyacetylene. J. Electron. Mater. 11, 471–490 (1982). https://doi.org/10.1007/BF02654684

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  • DOI: https://doi.org/10.1007/BF02654684

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