Skip to main content
Log in

A comparison of measurement techniques for determining phosphorus densities in semiconductor silicon

  • Published:
Journal of Electronic Materials Aims and scope Submit manuscript

Abstract

Phosphorus densities in semiconductor silicon slices cut from 14 single crystal ingots have been determined by two electrical and two analytical techniques. Hall effect measurements were made on specimens from all ingots, and junction capacitance-voltage measurements were made on specimens with densities up to about 5 × 1017 cm−3. Neutron activation analysis was used to measure phosphorus densities from 5 × 1015} to 5 x 1019} cm−3, and a photometric technique was used for densities greater than 1017 cm−3. A systematic discrepancy of about 15% between the photometric and neutron activation data is indicative of the interlaboratory agreement that might be realized in practice with these techniques.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Standard Method for Measuring Resistivity of Silicon Slices with a Collinear Four-Probe Array, ASTM Method F 84, Annual Book of ASTM Standards, Part 43 (November 1978).

  2. Standard Test Method for Measuring Radial Resistivity Variations on Silicon Slices, ASTM Method F 81, Annual Book of ASTM Standards, Part 43 (November 1978).

  3. K. G. Heinen and G. Larrabee, Anal. Chem.38, 1853 (1966).

    Article  CAS  Google Scholar 

  4. C. L. Luke and S. S. Flaschen, Anal. Chem.30, 1406 (1958).

    Article  CAS  Google Scholar 

  5. M. G. Buehler, Semiconductor Measurement Technology: Microelectronic Test Pattern NBS-3 for Evaluating the Resistivity-Dopant Density Relationship of Silicon, NBS Special Publication 400-22 (June 1976).

  6. M. G. Buehler and W. R. Thurber, IEEE Trans. Electron DevicesED-23, 968 (1976).

    Google Scholar 

  7. W. R. Thurber and M. G. Buehler, Semiconductor Measurement Technology: Microelectronic Test Pattern NBS-4, NBS Special Publication 400-32 (April 1978).

  8. R. L. Mattis and M. G. Buehler, Semiconductor Measurement Technology: A BASIC Program for Calculating Dopant Density Profiles from Capacitance-Voltage Data, NBS Special Publication 400-11 (June 1975).

  9. R. L. Mattis and M. G. Buehler, J. Electrochem. Soc.124, 1918 (1977).

    Article  CAS  Google Scholar 

  10. W. R. Thurber, R. L. Mattis, and Y. M. Liu, Semiconductor Characterization Techniques, Proceedings Volume 78-3, P. A. Barnes and G. A. Rozgonyi, Eds., pp. 81–92 (Electrochemical Society, Princeton, NJ, 1978).

    Google Scholar 

  11. Measuring Hall Mobility and Hall Coefficient in Extrinsic Semiconductor Single Crystals, ASTM Method F 76, Annual Book of ASTM Standards, Part 43 (November 1978).

  12. J. Messier and J. M. Flores, J. Phys. Chem. Solids24, 1539 (1963).

    Article  CAS  Google Scholar 

  13. P. Norton, T. Braggins, and H. Levinstein, Phys. Rev. B8, 5632 (1973).

    Article  CAS  Google Scholar 

  14. F. Mousty, P. Ostoja, and L. Passari, J. Appl. Phys.45, 4576 (1974).

    Article  CAS  Google Scholar 

  15. L. Esaki and Y. Miyahara, Solid-state Electron.1, 13 (1960).

    Article  Google Scholar 

  16. R. B. Fair, J. Electrochem. Soc.125, 323 (1978).

    Article  CAS  Google Scholar 

  17. S. S. Li and W. R. Thurber, Solid-state Electron.20, 609 (1977).

    Article  CAS  Google Scholar 

  18. J. C. Irvin, Bell System Tech. J.41, 387 (1962).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

This work was conducted as part of the Semiconductor Technology Program at NBS and was supported by the Defense Advanced Research Projects Agency (Order 2397). Not subject to copyright.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Thurber, W.R. A comparison of measurement techniques for determining phosphorus densities in semiconductor silicon. J. Electron. Mater. 9, 551–560 (1980). https://doi.org/10.1007/BF02652935

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02652935

Key words

Navigation