Abstract
A computer simulation procedure based on the Monte Carlo algorithm has been developed to study the thin film microstructure evolution in the Zone II regime. This is accomplished by letting the grain boundary movement on the film surface couple with the microstructure in the interior of the film. The grains when viewed in cross-section are found to reach a limiting size at which point all grain boundary motion ceases despite the presence of capillarity driving force. This results in a columnar morphology for the thin film. The cross-sectional size distribution function is found to be approximately log-normal in shape. The introduction of anisotropic solid-vapor interfacial energy is found to induce abnormal grain growth at the expense of the normal grain which has a relatively higher solid-vapor energy. An analytical model is proposed in which the formation of the columnar structure is explained in terms of the grain boundary drag at the growing interface due to sub-surface boundaries.
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Ling, S., Anderson, M.P. Development and evolution of thin film microstructures: A Monte Carlo approach. J. Electron. Mater. 17, 459–466 (1988). https://doi.org/10.1007/BF02652133
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DOI: https://doi.org/10.1007/BF02652133