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Influence of microalloying on the corrosion resistance of steel in saturated calcium hydroxide

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Abstract

The influence of microalloying vanadium or titanium on improving the corrosion resistance of mild steel in saturated calcium hydroxide solution was investigated. Potential-time, potentiodynamic polarization, and impedance measurement techniques were employed. The corrosion products have been examined by infrared and X-ray diffraction analysis and by scanning electron microscopy. It has been shown that the grain refining, due to microalloying, plays an important role in enhancing the corrosion resistance of steel. Scales of calcite and iron oxides on top of a protective oxide are formed on the investigated steels.

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References

  1. A.M. Sage:Metall. Technol., 1976, vol. 3, pp. 65–70.

    Google Scholar 

  2. S.S. Bhatnager, N.S. Datar, B.K. Guha, R. Chattopadhyay, and R.K. Sinha:Steel Furnace Monthly (Calcutta), 1977, vol. 12, pp. 466–473.

    Google Scholar 

  3. G. Watter:Microalloying 75, Proc. Conf., M. Korchynsky, ed., Union Carbide Corporation, New York, NY, 1977, pp. 622–633.

    Google Scholar 

  4. P. Beardmore:Mater. Eng., 1981, New York, NY, vol. 2, p. 250.

  5. A. Haberfield and R. Hudd:Metall. Mater. Technol., 1982, vol 14 p. 405.

    Google Scholar 

  6. H. Weise:Microalloying 75, Proc. Conf., M. Korchynsky, ed., Union Carbide Corporation, New York, NY, 1977, pp. 676–683.

    Google Scholar 

  7. S. Horejs, V. Smid, V. Navrat, T. Brnka, and R. Halbrstatova:Wire Industry, 1984, May, pp. 405–408.

  8. R. Halbrstatova, T. Brnka, V. Smid, and V. Navrat:HSLA Steels, Technology and Applications, Proc. Conf., ASM, Metals Park, OH, 1984, pp. 1049–1061.

    Google Scholar 

  9. C.W. Ramirez, B. Bargard, D. Jones, and Robert Heidersbach:Mater. Performance, 1990, Dec., pp. 33–39.

  10. H.G. Wheat and Z. Eliezer:Corrosion, 1987, vol. 43, pp. 126–128.

    CAS  Google Scholar 

  11. A.P. Akolzin, P. Ghosh, and Yu. Ya. Kharitonov:Br. Corros. J., 1985, vol. 20, pp. 32–35.

    CAS  Google Scholar 

  12. Corrosion of Metals in Association with Concrete, J.E. Slater, ed., ASTM-STP 818, ASTM, Philadelphia, PA, 1986, ch. 5.

    Google Scholar 

  13. J.A. Gonzalez and C. Andrade:Werkstoffe Korros., 1978, vol. 29, pp 515–518.

    Article  Google Scholar 

  14. D.G. John P.C. Searson, and J.L. Oawson:Br. Corros. J., 1981, vol. 16, pp. 102–106.

    Google Scholar 

  15. C.J. Newton and J.M. Sykes:Corros. Sci., 1988, vol. 28 (11), pp. 1051- 1074.

    Google Scholar 

  16. M.M. Eissa: Ph.D. Thesis, Cairo University, Cairo, Egypt, 1988.

    Google Scholar 

  17. F. Pickering and T. Gladman:Iron Steel Inst., 1963, vol. 81, pp. 10–25.

    Google Scholar 

  18. W.B. Morrison, B. Mintz, and R.C. Cochrane:Proc. Product Technology Conj. on Controlled Processing of HSLA, University of York, United Kingdom, 1976, BSC-reprint paper no. 1.

    Google Scholar 

  19. Basis of Electrochemical Impedance Spectroscopy, EG&G Princeton Applied Research, application note Ac-1 and references therein.

  20. G.W. Walter:Corros. Sci., 1986, vol. 26, pp. 681–703.

    Article  CAS  Google Scholar 

  21. C.T. Che, B.D. Cahan:J. Electrochem. Soc., 1982, vol. 129, pp. 17–25.

    Article  Google Scholar 

  22. J.F. Henriksen:Corrosion Sci., 1980, vol. 20, pp. 1241–1249.

    Article  CAS  Google Scholar 

  23. K.S. Rajagopalan, K. Vena, and K. Balakrishnan:J. Sci. Ind. Res., 1961, vol. 20D, p. 358.

    CAS  Google Scholar 

  24. K. Yenu, K. Balakrishnan, and K.S. Rajagoplan:Corros. Sci., 1965, vol. 5, p. 59.

    Article  Google Scholar 

  25. H. Oranowska and Z. Sklarska-Smialowska:Corros. Sci., 1981, vol. 21, pp. 735–747.

    Article  CAS  Google Scholar 

  26. M.M. Lamei: Ph.D. Thesis, Cairo University, Cairo, Egypt, 1993.

    Google Scholar 

  27. M. Durbin and P. Krahe: inProcessing and Properties of Low Carbon Steel, J. Gray, ed., AIME, New York, NY, 1973, pp. 109–131.

    Google Scholar 

  28. D. Gawne and G. Lewis:Mater. NY, Sci. Technol., 1985, vol. 1, pp. 183–191.

    CAS  Google Scholar 

  29. H.H. Uhlig:Corrosion and Corrosion Control, 1971, June, p. 373. $

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Hegazy, M.M., Eissa, M.M. Influence of microalloying on the corrosion resistance of steel in saturated calcium hydroxide. Metall Mater Trans A 27, 1701–1707 (1996). https://doi.org/10.1007/BF02649828

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