Abstract
The Fe-O system is well known experimentally and has a number of characteristic features in the liquid and solid phases—for example, extended solubility of the solid oxides, magnetic transitions, and a liquid miscibility gap. In this paper, these properties are described using the compound energy model with ionic constituents for the solid phases and an ionic two-sublattice model for the liquid. Parameters in these models are assessed to describe the experimental data, and a consistent set is determined that gives an accurate description of the properties from 298.15 to 2000 K.
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Cited References
F.J. Spencer and O. Kubaschewsld,Calphad, 2,147–167(1978).
R.J. Ackerman and R.W. Sandford, Jr., USAEC Rep. ANL 7250, Chemistry (TID-4500), Argonne, IL(1966).
L.S. Darken and R.W. Gurry,J. Am Chenu Soc., 67, 1398–1412 (1945).
I. Bransky and A. Z. Hed,J. Am. Ceram. Soc.,51, 231–232(1968).
F.E. Rizzo and J.V. Smith,J. Phys. Chem, 72, 485–488 (1968).
G.B. Barbi,J. Phys. Chem.,68, 2912–2916 (1964).
R.A Giddings and R.S. Gordon,J. Am Ceram. Soc.,56, 111–116 (1973).
R.L. Levin and J.B. Wagner, Jr.,Trans. Metall. Soc. AIME, 236, 516- 519(1966).
B. Swaroop and J.B. Wagner, Jr.,Trans. Metall. Soc. AIME, 239, 1215- 1218(1967).
RE. Rizzo, R.S. Gordon, and I.B. Cutler,J. Electrochem Soc.,116, 266–274(1969).
M.F. Marion,La Docum Met., (24), 87-129(1955).
J.R. Gavarri, C. Carel, and D. Weigel,J. Solid State Phys.,29, 81–95 (1979).
L.S. Darken and R.W. Gurry,J. Am Chem Soc.,68, 798–815 (1946).
0. Sjöden, S. Seetharaman, and L.-I. Staffansson,Metall Trans. B, 17, 179–184(1986).
E. Takayama and N. Kimizuka,J. Electrochem Soc.,127, 970–976 (1980).
C. Carel,Compt. Rend. Hebd C:Sci. Chim, 273, 393–395 (1971).
J.A. Barbero, MA Blesa, and A.J.G. Maroto,Z. Phys. Chem, 124, 139–147(1981).
S.S. Todd and K.R. Bonnickson,J. Am Chem Soc, 73, 3894–3895 (1951).
J.P. Coughlin, E.G. King, and K.R. Bonnickson,J. Am. Chem Soc.,73, 3891–3893(1951).
F. Grönvold and A. Sveen,J. Chem Thermodyn.,6, 859–872 (1974).
WA. Roth and W. Bertram,Z. Electrochem Angew. Phys. Chem, 35, 297–308(1929).
E.F. Wcstrum and F. Grönvold,J. Chem Thermodyn.,1, 543–557 (1969).
H. Esser, R. Averdick, and W. Grass,Arch. Eisenhüttenwes.,6, 289- 292(1933).
G.B. Barbi,J. Phys. Chem.,68, 1025–1029 (1964).
R. Dieckmann,Ber.Bunsenges. Phys. Chem.,86, 112–118(1982).
C.C. Wu andT.O. Mason,J. Am. Ceram. Soc.,64, 520–522(1981).
E. Jacobson and E. Rosén,Scand. J. Met.10, 39–43 (1981).
FJ. Norton, Rep. No. 55-RL-1248, General Electric Res. Lab. (1955).
F. Grönvold and E.J. Samuelsen,J. Phys. Chem Solids, 36, 249–256 (1975).
K. Krupka, personal communicationvia J. Haas (1974).
F. Grönvold and E.F. Westrum, Jr.,J. Am. Chem Soc.,81, 1780–1783 (1959).
E.S. Tankins, N.A Gokcen, and G.R. Belton,Trans. Metall. Soc. AIME, 230, 820(1964).
K. Schwerdtfeger,Trans. Metall. Soc. AIME, 239, 1276–1281 (1967).
C. Gatellier and M. Olette,Compt. Rend. C, 266, 1133 (1968).
M.N. Dastur and J. Chipman,Trans. Metall. Soc. AIME, 185, 441 (1949).
M.T. Hepworth, R.P. Smith, and E.T. Turkdogan,Trans. Metall. Soc. AIME, 236, 1278–1283(1966).
J.H. Swisher and E.T. Turkdogan,Trans. Metall. Soc. AIME, 239, 426- 431(1967).
I. Ansara and B. Sundman, SGTE, Proc. Conf. CODATA, Ottawa (1986).
T.I. Barry and F.P. Glasser, NPL Rep. DMA(A)169 (1988).
G. Inden,Z. Metallkd.,66, 577(1975).
M. Hillert and M. Jarl,Calphad, 2, 227–238(1978).
C.P. Chin, S. Hertzman, and B. Sundman, TRTTAMAC203 (1987).
A Fernandez-Guillermet and P. Gustafson,High Temp.—High Pres- sures, 16,591–610(1985).
M. Hillert, B. Jansson, and B. Sundman,Z Metallkd.,79, 81–87 (1988).
M. Hillert, B. Jansson, B. Sundman, and J. Ågren,Metall Trans. A, 16, 661–678(1985).
B. Jansson, thesis, Royal Institute of Technology, Stockholm (1984).
B. Sundman, B. Jansson, and J.O. Andersson,Calphad, 9,153–190 (1985).
M. Hillert, M. Selleby, and B. Sundman,Metall. Trans. A, 21, 2759- 2766(1990).
J. Campservaux, G. Boureau, C. Picard, and P. Gerdanian,Ann. Chim.,5, 250–260(1970).
A.A. Lykasov, Yu.S. Kuznetsov, E.I. Pil’ko, V.I. Shishkov, and V.A Kozheurov,Russ. J. Phys. Chem, 43,1754(1969).
H-J. Egnell.Arch. Eisenhüttenwes.,28, 109–115 (1957).
B. Touzelin,Rev. Int. Hautes Temp.,11, 219–230(1974).
P. Vallet and P. Raccah.Mém. Sci. Rev. Métall.,62, 1–29(1965).
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Sundman, B. An assessment of the Fe-O system. JPE 12, 127–140 (1991). https://doi.org/10.1007/BF02645709
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DOI: https://doi.org/10.1007/BF02645709