Abstract
The present study uses plasma spray technology as a production process for the fabrication of free- stand-ing, near- net- shaped NiAl components. Attention is especially focused on the in situ synthesis of NiAl. A new internal, dual powder injector blade has been designed to improve the gun performance as well as the spray efficiency of the feedstock powder. The specific role of the substrate (i.e., its shape and material) for the successful spray forming of free- standing parts is studied. The as- sprayed parts were subjected to a post- heat- treatment and hot isostatic pressing. Subsequently, they were metallographically inspected. The mechanical properties, such as hardness, Young’s moduli, and the fracture behavior during four-point bending, are also examined.
Similar content being viewed by others
References
R. Darolia, NiAl Alloys for High-Temperature Structural Applications,J. Met., Vol 43 (No. 3), 1991, p 44–49
G. Sauthoff, Intermetallic Phases as High Temperature Materials,Z. Metallkunde, Bd. 77, H. 10,1986, p 654-666
G. Sauthoff, Intermetallic Phases—Materials Development and Prospect,Z. Metallkunde, Bd. 80, H. 5,1989, p 337-344
S. Dallaire, Plasma Spray Forming of Coatings and Parts,CIM Bulletin, Vol 80 (No. 900), 1987, p 37–42
H. Herman, Plasma-Sprayed Coatings,Sci. Am., Vol 9,1988, p 78–83
A. Geibel, P. Verstreken, L. Froyen, O. van der Biest, L. Delaey, M. Poorteman, P. Barbary, and F. Cambier, Plasma Processing of Ceramic and Metallic Materials,Atb Metallurgie, 1990, p 111 -119
M.I. Boulos,International Summer School on Plasma Chemistry, P. Fauchais, Ed., Italy, Sept 1989
A. Guinier,Théorie et Technique de la Radiocristallographie, 2nd en., Dunod, Paris, 1956, p 396
R.D. Cullity, Elements of X-ray Diffraction, Addison-Wesley, 1967, p 363-375
R.D. Noebe, R.R. Bowman, and M. V. Nathal, Physical and Mechanical Properties of the B2 Compound NiAl,Int. Mat. Rev.1, Vol 38 (No. 4), 1993, p 193–232
E. Macherauch,Praktikum in Werkstoffkunde, Auflage, Vieweg & Sohn, Braunschweig/Wiesbaden, 1989, p 224–228
Metals—Mechanical Testing: Elevated and Low Temperature Tests,Annual Handbook of ASTM Standards, Vol 03.01, Section 3, E 855, ASTM, 1984, p 788-803
O. Knotek, E. Lugscheider, and K.-H. Cremer, Alumina and Aluminide Formation in Nickel-Aluminum Spraying Powders, Paper 60,Proc. Ninth Int. Spray Conference, 1980, p 281-286
G.J. Ackland and V. Vitek, Effect of Ordering Energy on Grain Boundary Structure in L12 Alloys,High Temperature Ordered Intermetallic Alloys III, C.T. Liu et al., Ed., MRS Symposium Proceedings, Vol 133, MRS, 1989, p 105–111
R. McPherson, A Model for the Thermal Conductivity of Plasma Sprayed Ceramic Coatings,Thin Solid Films, Vol 112,1984, p 89–95
R.K. Williams, R.S. Graves, F.J. Weavers and D.L. McElroy, Physical Properties of Ni3Al Containing 24 and 25 Atomic Percent Aluminium,High Temperature Ordered Intermetallic Alloys, C.C. Koch et al., Ed., MRS Symposium Proceedings, Vol 39, MRS, 1985, p 505–511
W.S. Walston and R. Darolia, Effects of Alloying on Physical Properties of NiAl,High Temperature Ordered Intermetallic Alloys V, I. Baker et al., Ed., MRS Symposium Proceedings, Vol 288, MRS, 1993, p 237–242
H. Jacobi, Die Optischen Eigenschaften der Beta-Phase NiAl,Z Metallkunde, Vol 60,1969, p 106
K.-H. Cremer, Zur Reaktionskinetik von Nickel-Aluminium- Flammspritzpulvern, doctoral thesis, Rheinisch-Westfälische Technische Hochschule Aachen, Aachen, Germany, 1979
S. Sampath, G.A. Bancke, H. Herman, and R. Rangaswamy, Plasma Sprayed Ni-Al Coatings,Surf. Eng., Vol 5 (No. 4), 1989, p 293–298
V. Kuznetsov, Aluminium-Nickel-Oxygen,Ternary Alloys: A Comprehensive Compendium of Evaluated Constitutional Data, Vol 7, G. Petzow and G. Effenberg, Ed., VCH Verlagsgesellschaft, Weinheim, BRD, 1993, p 434
A. Taylor and N.J. Doyle, Further Studies on the Nickel-Aluminum System, Part I: The β-NiAl and δ-Ni2Al3 Phase Field,J. Appl. Cryst., No. 5,1972, p 201–209
I. Baker and P.R. Munroe, Properties of B2 Compounds,High Temperature Aluminides and Intermetallics, S.H. Whang et al., Ed., The Mineral, Metal & Materials Society, 1990, p 425-452
R. Hutchings, M.H. Loretto, and R.E. Smallman, Oxidation of Inter- metallic Compounds NiAl,Metal Sci., Vol 1,1981, p 7–13
M. Vardelle, A. Vardelle, and P. Fauchais, Spray Parameter and Particle Behavior Relationships during Plasma Spraying,J. Therm. Spray Technol., Vol 2 (No. 1), 1993, p 79–92
R.W. Smith and D. Apelian, Melting Phenomena of Several Nickel Based Alloys in a Plasma Jet Operating at Low Pressure, MRS Symposium Proceedings, Vol 98,1987, p 89–98
R.W. Smith, Particle Melting Behavior in a D.C. Plasma Jet: Observations on Several Nickel Based Alloys,Thermal Spray Technology— New Ideas and Processes, ASM International, 1988, p 123–128
R. Bohn, T. Haubold, R. Birringer, and H. Gleiter, Nanocrystalline hi- termetallic Compounds—An Approach to Ductility?Scripta Metall., Vol 25 (No. 4), 1991, p 811–816
X.R. Qian and Y.T. Chou, The Effect of Boron on Microhardness in Ni3Al Polycrystals,High Temperature Ordered Intermetallic Alloys III, C.T. Liu et al., Ed. MRS Symposium Proceedings, Vol 133, MRS, 1989, p 529–536
E.M. Schulson and D.R. Barker, A Brittle to Ductile Transition in NiAl of a Critical Grain Size,Scripta Metall, Vol 17,1983, p 519–522
N.S. Stoloff, Ordered Alloys for High Temperature Applications,High Temperature Ordered Intermetallic Alloys, C.C. Koch et al.. Ed., MRS Symposium Proceedings, Vol 39, MRS, 1985, p 3–27
K. Murakami, T. Okamoto, and Y, Miyamoto, Rapid Solidification and Self-Annealing of Fe-C-Si Alloys by Low Pressure Plasma Spraying,Mat. Sci. Eng., Vol A117,1989, p 207–214
R.H. Unger, Comparison of Thermal Spray Bond Coats,Proc. Nat. Therm. Spray Conf., D.L. Houck, Ed., Orlando, FL, 1987, p 365–370
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Geibel, A., Froyen, L., Delaey, L. et al. Plasma spray forming: An alternate route for manufacturing free-standing components. JTST 5, 419–430 (1996). https://doi.org/10.1007/BF02645272
Issue Date:
DOI: https://doi.org/10.1007/BF02645272