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Enthalpies of formation of the Ag- Au- Si, Ag- Au- Ge, and Ag- Au- Sn Ternary Liquid Alloys; experimental determinations and application of the hoch- arpshofen model

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Abstract

The enthalpies of formation of the Ag-Au-Si, Ag-Au-Ge, and Ag-Au-Sn ternary liquid alloys were measured by very high-temperature calorimetry. Measurements were carried out between 1373 and 1550 K and enthalpies were obtained with an accuracy of 8 pct. Then the same ternary enthalpies of formation were calculated using the Hoch-Arpshofen model, and a comparison between experi-mental and calculated values was performed on the whole composition range.

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Authors and Affiliations

  1. Université de Provence, C.N.R.S. UA 1168, Laboratoire S.E.T.T., Centre de St-Jér>ome, Avenue Escadrille Normandie Niemen, 13397 Marseille Cedex 13, France

    S. Hassam (Research Associate), M. Gaune-Escard (Director of Research) & J. P. Bros (Professor of Chemistry)

  2. Department of Ma- terials Science and Engineering, University of Cincinnati, 45221-0012, Cincinnati, OH

    M. Hoch (Professor of Materials Science)

Authors
  1. S. Hassam
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  2. M. Gaune-Escard
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  3. J. P. Bros
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  4. M. Hoch
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Hassam, S., Gaune-Escard, M., Bros, J.P. et al. Enthalpies of formation of the Ag- Au- Si, Ag- Au- Ge, and Ag- Au- Sn Ternary Liquid Alloys; experimental determinations and application of the hoch- arpshofen model. Metall Trans A 19, 2075–2089 (1988). https://doi.org/10.1007/BF02645210

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  • DOI: https://doi.org/10.1007/BF02645210

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