Abstract
The allotropic transformation of cobalt was studied with a differential scanning calorimeter. The temperatures of the fcc to hep transformation, As, and fcc to hcp transformation, Ms, exhibit a linear dependence on the heating and cooling rates: As(K) = 723.2 + 0.28R and Ms(K) = 671.4-0.28R whereR is the rate in K/min. As, Ms, and the associated enthalpies of the phase changes were observed to increase with increasing number of cycles through the transformation. The Ms reaction was observed to proceed slowly isothermally while exhibiting athermal behavior when cooled rapidly.
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Ray, A., Smith, S. & Scofield, J. Study of the phase transformation of cobalt. JPE 12, 644–647 (1991). https://doi.org/10.1007/BF02645161
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DOI: https://doi.org/10.1007/BF02645161