Abstract
A number of copper-base alloys (Cu-Al, Cu-Al-Ni) have been processed by chill block melt spinning and planar flow casting. A range of processing conditions was employed to observe how these affected the subsequent transformation behavior of these alloys. Characteristic transformation temperatures were analyzed in a differential scanning calorimeter and structures examined by both scanning and transmission electron microscopy. The high transformation temperatures of Cu-Al alloys made them unsuitable for monitoring the effect of process conditions. Cu-Al-Ni alloys withM s temperatures around room temperature are sensitive to both wheel material and provision of secondary quenching facilities. Some alloys containing titanium did not exhibit a shape memory phenomenon after rapid quenching. Heat treatment of alloys in the β and β1 phase fields was undertaken. β phase annealing resulted in grain growth and an increase inM s , while in the β1 phase, stabilization of transformation temperatures could be obtained below 300 °C. The effect of low stresses was also monitored in a thermo-mechanical analyzer (TMA).
Similar content being viewed by others
References
H. Tas, L. Delaey, and A. Deruyttere:J. Less Common Metals, 1972, vol. 28, pp. 141–51.
L. Delaey, R. V. Krishnan, H. Tas, and H. Warlimont:J. Mater. Sci., 1974, vol. 9, pp. 1521–55.
Z. Nishiyama:Martensitic Transformation, Academic Press, New York, NY, 1978.
J. Perkins, ed.:Shape Memory Effects in Alloys, Plenum Press, New York, NY, 1975.
C. M. Wayman: inPhase Transformations, Institution of Metallurgists, London, 1979, vol. 1, pp. IV-1 to IV-21.
C. M. Wayman:J. Metals, 1980, vol. 36(6), pp. 129–37.
H. Jones and C. Suryanarayana:J. Mater. Sci., 1973, vol. 8, pp. 705–53.
C. Suryanarayana:Rapidly Quenched Metals — a Bibliography 1973–1979, IFI/Plenum Press, New York, NY, 1980.
H. Herman, ed.:Ultrarapid Quenching of Liquid Alloys, Academic Press, New York, NY, 1981.
H. Jones:Rapid Solidification of Metals and Alloys, Monograph 8, The Institution of Metallurgists, London, 1982.
W. M. Stobbs and J. V. Wood:Acta Metall., 1979, vol. 27, pp. 575–84.
J. V. Wood, A. Crossley, and W. M. Stobbs: inProc. 3rd Int. Conf. on Rapidly Quenched Metals, B. Cantor, ed., Metals Society, London, 1978, pp. 180–87.
J. Perkins, J. J. Rayment, B. Cantor, and R. W. Cahn:Scripta Metall., 1981, vol. 15, pp. 771–76.
G. Thomas and R. H. Willens:Acta Metall., 1964, vol. 12, pp. 191–96.
P. K. Rastogi and K. Mukherjee:Metall. Trans., 1970, vol. 1, pp. 2115–17.
G. F. Boiling and D. Fainstein:Phil. Mag., 1972, vol. 25, pp. 45–66.
J. V. Wood and R. W. K. Honeycombe:J. Mater. Sci., 1974, vol. 9, pp. 1183–88.
P. Furrer and H. Warlimont:Z Metallkunde, 1973, vol. 64, pp. 236–48.
J. V. Wood and R. W. K. Honeycombe:Phil. Mag., 1978, vol. 37, pp. 501–15.
S. P. Gupta:Mater. Sci. and Eng., 1972, vol. 10, pp. 341–56.
P. L. Ferraglio and K. Mukherjee:Acta Metall., 1974, vol. 22, pp. 835–45.
R. E. Hummel, J. W. Kroyer, and W. Pasupathi:Trans. TMS-AIME, 1968, vol. 241, p. 249.
J. V. Wood and W. M. Stobbs: inPhase Transformations, Institution of Metallurgists, London, 1979, vol. 2, pp. IV-20 to IV-22.
J. V. Wood:Scripta Metall., 1982, vol. 16, pp. 271–74.
P. G. Boswell and G. A. Chadwick:Scripta Metall., 1977, vol. 11, pp. 459–65.
R. C. Ruhl:Mater. Sci. Eng., 1967, vol. 1, pp. 313–20.
J. V. Wood, J. K. Bingham, and J. V. Bee: as Ref. 12, pp. 94–101.
L. Delaey, A. J. Perkins, and T. B. Massalski:J. Mater. Sci., 1972, vol. 7, pp. 1197–1215.
H. Kubo and C. M. Wayman:Metall. Trans. A, 1979, vol. 10A, pp. 633–43.
H. Kubo, I. Cornells, and C. M. Wayman:Acta Metall., 1980, vol. 28, pp. 405–16.
J. V. Wood, P. F. Mills, J. K. Bingham, and J. V. Bee:Metall. Trans. A, 1979, vol. 10A, pp. 575–84.
J. V. Wood, P. F. Mills, A. R. Waugh, and J. V. Bee:J. Mater. Sci., 1980, vol. 15, pp. 2709–19.
H. Kubo and C. M. Wayman:Acta Metall., 1980, vol. 28, pp. 395–404.
D. E. Polk, A. Calka, and B.C. Giessen:Acta Metall., 1978, vol. 26, pp. 1097–1103.
K. Otsuka, H. Sakamoto, and K. Shimizu:Acta Metall., 1979, vol. 27, pp. 585–601.
A. Prasetyo, F. Reynaud, and H. Warlimont:Acta Metall., 1976, vol. 24, pp. 1009–16.
D. H. Warrington, H. A. Davies, and N. Shohoji:Proc 4th Int. Conf. on Rapidly Quenched Metals, T. Masumoto and K. Suzuki, eds., Japan Inst. Metals, Sendai, 1982, pp. 69–72.
D. Schofield and P. Miodownik:Metals Tech., 1980, vol. 7, pp. 167–73.
A. Nagasawa and K. Kawachi:J. Phys. Soc. Japan, 1970, vol. 30, p. 296.
H. Tas, L. Delaey, and A. Deruyttere:Scripta Metall., 1971, vol. 5, pp. 1117–24.
M. Hansen and K. Anderko:Constitution of Binary Alloys, 2nd edition, McGraw-Hill, New York, NY, 1958, p. 86.
J. V. Wood and K. Akhurst:J. Mater. Sci., 1976, vol. 11, pp. 2142–45.
J. V. Wood and S. C. King:J. Mater. Sci., 1978, vol. 13, pp. 119–24.
F. Nakamura, J. Kusiu, Y. Shimizu, and J. Takamura:J. Japan Inst. of Metals., 1980, vol. 44, pp. 1302–11.
J. Peitikainen: inProc. ICOMAT82, J. Physique (supp. 12), C4–479.
E. Hornbogen and W. Mayer:Acta Metall., 1967, vol. 15, pp. 983–88.
E. Laine and E. Hiltuner:Scripta Metall., 1982, vol. 16, pp. 399–400.
H. Otsuka, H. Sakamoto, and K. Shimizu:Scripta Metall., 1976, vol. 10, pp. 983–88.
H. Warlimont, L. Delaey, R. V. Krishnan, and H. Tas:J. Mater. Sci., 1974, vol. 9, pp. 1545–55.
W. L. Peterson and S. J. Rothman:Phys. Rev., 1970, vol. B1, p. 3264.
K. Monma, H. Suto, and H. Oikawa:J. Japan Inst. Metals, 1964, vol. 28, p. 188.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Wood, J.V., Shingu, P.H. The effect of processing conditions and subsequent heat treatment on the transformation behavior of some rapidly solidified copper-base shape memory alloys. Metall Trans A 15, 471–480 (1984). https://doi.org/10.1007/BF02644970
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02644970