Abstract
Laboratory-scale investigations of a novel hydrometallurgical process for lead production are described. The process is based upon the solubility of certain oxidized lead compounds in aqueous ammoniacal ammonium sulfate (AAS) solutions. There are, essentially, five steps in the process, viz: pretreatment to convert lead in the raw material to a suitable oxidized form; dissolution of the lead compounds in an AAS solution at ambient temperatures and pressures; recovery of the lead from solution by electrolysis or precipitation; conversion of the products of the preceding stage to saleable products; treatment of solutions to make them suitable for recycling. This new process avoids many of the difficulties of existing hydrometallurgical processes for lead.
Similar content being viewed by others
References
F. A. Forward and I. H. Warren:Met. Rev., 1960, vol. 5, pp. 137–64.
F. Pawlek: German Patent 888,929,1953.
0. C. Ralston:AIME Trans., 1924, vol. 70, pp. 447–70.
F. A. Forward: Fifth International Mineral Processing Congress, Paper No. 40, Inst. of Mining and Metallurgy, London 1960.
L. S. Getskin, V. V. Yatsuk, and A. P. Panteleeva:Tsvetnye Metaly, English Ed.,May 1965, pp. 24–26.
J. C. Long:J. Amer. Chem. Soc., 1899, vol. 22, pp. 217–18.
A. W. Allen:Eng. Min. J., 1926, vol. 121, pp. 112–13.
O. F. Marvin: U.S. Patent 3,196,001,1965.
R. W. Pickering and J. S. Pidgeon: U.S. Patent 3,440,155,1969.
E. Discher and F. Pawlek:Z. Erzbergbau u. Metallhuettenw., 1957, vol. 10, pp. 158–66.
A. I. Vizolyi, H. Veltman, and F. A. Forward:Trans. TMS-AIME, 1963, vol. 227, pp. 215–20.
T. R. Scott: Private communication, November 1965, Dept. of Mineral Chemistry, C.S.I.R.O., Melbourne.
G. C. Bratt and R. J. Sinclair: Australian Patent Application.
T. R. Scott: Australian Patent Application.
G. C. Bratt and A. R. Ault: Australian Patent Application.
G. C. Bratt and D. W. Brown: Australian Patent Application.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bratt, G.C., Pickering, R.W. Production of lead via ammoniacal ammonium sulfate leaching. Metall Trans 1, 2141–2149 (1970). https://doi.org/10.1007/BF02643427
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02643427