Skip to main content
Log in

Production of lead via ammoniacal ammonium sulfate leaching

  • Published:
Metallurgical Transactions Aims and scope Submit manuscript

Abstract

Laboratory-scale investigations of a novel hydrometallurgical process for lead production are described. The process is based upon the solubility of certain oxidized lead compounds in aqueous ammoniacal ammonium sulfate (AAS) solutions. There are, essentially, five steps in the process, viz: pretreatment to convert lead in the raw material to a suitable oxidized form; dissolution of the lead compounds in an AAS solution at ambient temperatures and pressures; recovery of the lead from solution by electrolysis or precipitation; conversion of the products of the preceding stage to saleable products; treatment of solutions to make them suitable for recycling. This new process avoids many of the difficulties of existing hydrometallurgical processes for lead.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. F. A. Forward and I. H. Warren:Met. Rev., 1960, vol. 5, pp. 137–64.

    CAS  Google Scholar 

  2. F. Pawlek: German Patent 888,929,1953.

  3. 0. C. Ralston:AIME Trans., 1924, vol. 70, pp. 447–70.

    Google Scholar 

  4. F. A. Forward: Fifth International Mineral Processing Congress, Paper No. 40, Inst. of Mining and Metallurgy, London 1960.

    Google Scholar 

  5. L. S. Getskin, V. V. Yatsuk, and A. P. Panteleeva:Tsvetnye Metaly, English Ed.,May 1965, pp. 24–26.

  6. J. C. Long:J. Amer. Chem. Soc., 1899, vol. 22, pp. 217–18.

    CAS  Google Scholar 

  7. A. W. Allen:Eng. Min. J., 1926, vol. 121, pp. 112–13.

    Google Scholar 

  8. O. F. Marvin: U.S. Patent 3,196,001,1965.

  9. R. W. Pickering and J. S. Pidgeon: U.S. Patent 3,440,155,1969.

  10. E. Discher and F. Pawlek:Z. Erzbergbau u. Metallhuettenw., 1957, vol. 10, pp. 158–66.

    CAS  Google Scholar 

  11. A. I. Vizolyi, H. Veltman, and F. A. Forward:Trans. TMS-AIME, 1963, vol. 227, pp. 215–20.

    Google Scholar 

  12. T. R. Scott: Private communication, November 1965, Dept. of Mineral Chemistry, C.S.I.R.O., Melbourne.

  13. G. C. Bratt and R. J. Sinclair: Australian Patent Application.

  14. T. R. Scott: Australian Patent Application.

  15. G. C. Bratt and A. R. Ault: Australian Patent Application.

  16. G. C. Bratt and D. W. Brown: Australian Patent Application.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bratt, G.C., Pickering, R.W. Production of lead via ammoniacal ammonium sulfate leaching. Metall Trans 1, 2141–2149 (1970). https://doi.org/10.1007/BF02643427

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02643427

Keywords

Navigation