Metallurgical Transactions

, Volume 3, Issue 7, pp 1913–1918

Prediction of activities of oxygen in dilute quaternary solutions using binary data

  • K. T. Jacob
  • C. B. Alcock
Process Metallurgy

DOI: 10.1007/BF02642578

Cite this article as:
Jacob, K.T. & Alcock, C.B. MT (1972) 3: 1913. doi:10.1007/BF02642578


Equations are developed for predicting the activity coefficients of oxygen dissolved in ternary liquid alloys. These are extensions of earlier treatments, and are based on a model in which each oxygen atom is assumed to make four bonds with neighboring metal atoms. It is also postulated that the strong oxygen-metal bonds distort the electronic configuration around the metal atoms bonded to oxygen, and that the quantitative reduction of the strength of bonds made by these atoms with all of the adjacent metal atoms is equivalent to a factor of approximately two. The predictions of the quasichemical equation which is derived agree satisfactorily with the partial molar free energies of oxygen in Ag-Cu-Sn solutions at 1200°C reported in literature. An extension of this treatment to multicomponent solutions is also indicated.

Copyright information

© The Metallurgical of Society of AIME 1972

Authors and Affiliations

  • K. T. Jacob
    • 1
  • C. B. Alcock
    • 1
  1. 1.Department of Metallurgy and Materials ScienceUniversity of TorontoTorontoCanada

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