Skip to main content
SpringerLink
Log in

Thermal and structural properties of coordination compounds of 2-mercapto-1-methylimidazole with palladium(II) and platinum(II)

  • Published:
Journal of thermal analysis Aims and scope Submit manuscript

Abstract

Complexes of 2-mercapto-1-methylimidazole (TMZ) with PdII and PtII of the general formula M(TMZ)nX2 (whereM=Pd, Pt andX=Cl, Br, I or SO4 andn=2 or 4) were obtained. The thermal stabilities of the compounds were estimated by derivatographic measurements and lattice constants were estimated from their X-ray powder diffraction patterns.

Zusammenfassung

Komplexe von 2-Merkapto-1-methylimidazol (TMZ) mit PdII und PtII der allgemeinen Formel M(TMZ)nX2 (mitM=Pd, Pt undX=Cl, Br, I oder SO4 undn=2 oder 4) wurden hergestellt. Mittels derivatografischen Messungen wurde die thermische Stabilität der Verbindungen geschätzt und anhand von Debye-Scherrer-Aufnahmen Gitterkonstanten geschäzt.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. W. Hay, Bio-Inorganic Chemistry, Ellis Horwood Ltd., Publisher, Market Cross House, Chichester 1987.

    Google Scholar 

  2. K. Maskos, Wiadomosci Chemiczne, 35 (1981) 735.

    CAS  Google Scholar 

  3. M. Z. Wisniewski, W. J. Surga and B. Lenarcik, Transition Met. Chem., 15 (1990) 63.

    Article  CAS  Google Scholar 

  4. S. E. Livingstone, The Chemistry of Ruthenium, Rhodium. Palladium, Osmium, Iridium and Platinum, Pergamon Press, Oxford, New York, Toronto, Sydney and Paris 1973, p. 274.

    Google Scholar 

  5. Powder Diffraction File, JCPDS: International Centre for Diffraction Data, 1601 Park Lane, Swarthmore, PA 19801, Data 1988, File No. 5-681.

  6. Powder Diffraction File, JCPDS: International Centre for Diffraction Data, 1601 Park Lane, Swarthmore, PA 19801, Data 1988, File No. 4-807.

  7. J. W. Visser, J. Appl. Crystallogr., 2 (1969) 89, version 12.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, Pedagogical University, ul. Chęcińska 5, 25-020, Kielce, Poland

    W. J. Surga, M. Z. Wisniewski & A. G. Adach

Authors
  1. W. J. Surga
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Z. Wisniewski
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. G. Adach
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Surga, W.J., Wisniewski, M.Z. & Adach, A.G. Thermal and structural properties of coordination compounds of 2-mercapto-1-methylimidazole with palladium(II) and platinum(II). Journal of Thermal Analysis 44, 697–705 (1995). https://doi.org/10.1007/BF02636287

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02636287

Keywords

Search

Navigation