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Studies on thermokinetics of consecutive first-order reactions

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Abstract

The transformation equation for the thermokinetics of consecutive first-order reactions has been deduced, and a thermokinetic research method of irreversible consecutive first-order reactions, which can be used to determine the rate constants of two steps simultaneously, is proposed. The method was validated and its theoretical basis was verified by the experimental results.

Zusammenfassung

Die Transformationsgleichung für die Thermokinetik konsekutiver Reaktionen erster Ordnung wurde abgeleitet und es wurde eine thermokinetische Untersuchungsmethode für irreversible konsekutive Reaktionen erster Ordnung vorgeschlagen, bei der die Geschwindigkeitskonstante zweier Schritte simultan bestimmt werden kann. Die Methode wurde bestätigt und die theoretischen Grundlagen durch experimentelle Ergebnisse überprüft.

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Authors and Affiliations

  1. Department of Chemistry, Sichuan University, 610064, Chengdu, P.R. China

    J. Liu, X. Zeng, Y. Deng & A. Tian

Authors
  1. J. Liu
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  2. X. Zeng
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  3. Y. Deng
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  4. A. Tian
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Liu, J., Zeng, X., Deng, Y. et al. Studies on thermokinetics of consecutive first-order reactions. Journal of Thermal Analysis 44, 617–627 (1995). https://doi.org/10.1007/BF02636281

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  • DOI: https://doi.org/10.1007/BF02636281

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