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Direct potentiometric titration of oxirane oxygen by hydrogen chloride-acetic acid

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Journal of the American Oil Chemists Society

Summary

A new direct potentiometric titration method for the determination of oxirane oxygen has been developed. This method is applicable to a great variety of epoxy compounds and epoxy plasticizers. Carboxyl groups do not interfere, and a greater accuracy and reproducibility are obtained than in any of the indirect methods used.

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References

  1. Blumrich, K., Angew. Chem.,54, 374–5 (1941).

    CAS  Google Scholar 

  2. Bradley, T. F., U. S. Patent 2,500,600 (1950) to Shell Development Company.

  3. Culvenor, C. C. J., Davies, W., and Heath, N. S., J. Chem. Soc., 278–82 (1949).

  4. Deckert, W., Z. anal. Chem.,82, 297 (1930);109, 166 (1937).

    Article  CAS  Google Scholar 

  5. Gasson, E. J., Millidge, A. F., Primavesi, G. R., Webster, W., and Young, D. P., J. Chem. Soc., 2161–9 (1954).

  6. Hilton, F., Trans, Inst. Rubber Ind.,17, 319–32 (1941).

    Google Scholar 

  7. King, G., J. Chem. Soc., 1980–84 (1951).

  8. Metzger, K., “Beitrag zur quantitativen Bestimmung des Äthylenoids,” U.S.T.O.M., Reel 15, Bag 3043 (1938), p. 2266.

    Google Scholar 

  9. Nicolet, B. H., and Poulter, T. C., J. Am. Chem. Soc.,52, 1186–91 (1930).

    Article  CAS  Google Scholar 

  10. Swan, J. D., Anal. Chem.,26, 878–80 (1954).

    Article  CAS  Google Scholar 

  11. Swern, Daniel, Findley, T. W., Billen, G. N., and Scanlan, J. T., Anal. Chem.,19, 414–15 (1947).

    Article  CAS  Google Scholar 

  12. Tchitchibabine, A., and Bestongeff, M., Chem. Zentr.,106, I. 3916 (1935).

    Google Scholar 

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Durbetaki, A.J. Direct potentiometric titration of oxirane oxygen by hydrogen chloride-acetic acid. J Am Oil Chem Soc 33, 221–223 (1956). https://doi.org/10.1007/BF02632266

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  • DOI: https://doi.org/10.1007/BF02632266

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