Abstract
Two crystal modifications, I and II, of the ZnPhen(S2CNEt2)2 complex have been isolated. According to XRD data, the single crystals of I are triclinic with a=9.745(2), b=10.252(2), c=14.331(3) Å, α=99.18(2), β=91.01(2), γ=113.28(2)°, V=1293.2(4) Å3, space group P1, Z=2, dcalc=1.401 g/cm3. The crystals of II are monoclinic with a=7.220(6), b=18.095(2), c=19.050(4) Å, β=95.85(2)°, V=2475.8(7) Å3, space group C2/c, Z=4, dcalc=1.461 g/cm3. In both modifications, the structure is formed by monomer molecules with a distorted octahedral environment of the zinc atom. All atoms in I are in the general position; in II, the atoms are linked by the twofold rotation axis. It is shown by X-ray phase analysis (XRPA) that the MnPhen(S2CNEt2)2 complexes (III) are isostructural to modification I of the ZnPhen(S2CNEt2)2 complex, which underlies the synthesis of a solid solution of these complexes, MnZn2Phen3(S2CNEt2)6 (phase IV). It is found that MPhen(S2CNEt2)2 (M=Zn2+, Mn2+) and phase IV quantitatively sublime when heated in vacuum. Thermolysis of III in argon yields manganese(II) sulfide of cubic modification; the main product of thermolysis of phase IV is a solid solution of ZnxMn1−xS of hexagonal modification.
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References
S. V. Larionov,Zh. Neorg. Khim.,24, No. 6, 1446–1456 (1979).
S. V. Larionov, —ibid.,38, No. 10, 1616–1624 (1993).
S. V. Larionov, V. N. Kirichenko, S. M. Zemskova, and I. M. Oglezneva,Koordinats. Khim.,16, No. 1, 79–84 (1990).
S. V. Larionov, L. A. Kosareva, S. M. Zemskova, and P. E. L'vov,Proceedings of the 12th Conference on Coordination Chemistry, Solenice, ChSSR, 209–214 (1989).
L. A. Glinskaya, R. F. Klevtsova, and S. M. Zemskova,Zh. Strukt. Khim.,33, No. 1, 106–114 (1992).
S. M. Zemskova, L. A. Glinskaya, V. B. Durasov, et al., —ibid.,34, No. 5, 157–166 (1993).
D. G. Holah and C. N. Murphy,Can. J. Chem.,49, No. 16, 2726–2732 (1971).
V. M. Shulman, S. V. Larionov, V. E. Fedorov, and L. A. Patrina,Zh. Neorg. Khim.,18, No. 12, 2985–2989 (1973).
R. G. Gerr, A. N. Yanovskii, and Yu. T. Struchkov,Kristallografiya,28, No. 5, 1029 (1983).
S. M. Zemskova, L. A. Glinskaya, R. F. Klevtsova, and S. V. Larionov,Zh. Neorg. Khim.,38, No. 3, 466–471 (1993).
V. N. Kirichenko, L. A. Glinskaya, R. F. Klevtsova, et al.,Zh. Strukt. Khim.,35, No. 2, 106–111 (1994).
L. A. Glinskaya, S. M. Zemskova, R. F. Klevtsova, et al.,Polyhedron,11, No. 22, 2951–2956 (1992).
G. M. Zhidomirov, S. N. Lebedev, S. N. Dobryakov, et al.,Interpretation of Complex ESR Spectra [in Russian], Nauka, Moscow (1975).
S. V. Larionov, L. A. Patrina, E. M. Uskov, and O. G. Potapova, USSR Patent No. 736548, Method for the Preparation of Solid Solutions of Antimony and Bismuth Sulfides, Russian Bulletin of Inventions, No. 4, 218 (1991).
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Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 36, No. 3, pp. 528–540, May–June, 1995.
Translated by L. Smolina
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Zemskova, S.M., Glinskaya, L.A., Klevtsova, R.F. et al. Volatile ZnPhen(S2CNEt2)2 and MnPhen(S2CNEt2)2 complexes and the MnZn2Phen3(S2CNEt2)6 phase: Thermal behavior and crystal and molecular structures of two modifications of ZnPhen(S2CNEt2)2 . J Struct Chem 36, 484–495 (1995). https://doi.org/10.1007/BF02578536
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DOI: https://doi.org/10.1007/BF02578536