Skip to main content
Log in

Complementarity and justification in science, or comments on some fundamental concepts and problems in the theory and methods of structure and property investigations of complex molecules and molecular systems

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Major problems in using some key notions of the theory of structure, such as bond length and potential function parameters, are discussed on the basis of the general complementarity principle formulated by Bohr. It is shown that the use of this principle and model representations, indispensable in microworld studies, inevitably involves subjectivism arising in the solution of inverse problems, and leads to the violation of the requirement of reason.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. L. A. Gribov,J. Mol. Struct.,272 111–131 (1992).

    Article  CAS  Google Scholar 

  2. M. E. Elyashberg, L. A. Gribov, and V. V. Serov,Computer-Aided Molecular Spectral Analysis [in Russian], Nauka, Moscow (1980).

    Google Scholar 

  3. N. A. B. Gray,Computer-Assisted Structure Elucidation, Wiley and Sons, New York (1986).

    Google Scholar 

  4. N. Bohr,Selected Scientific Papers, Vol. 2, [Russian translation], Nauka, Moscow (1971).

    Google Scholar 

  5. N. Bohr,Nature, Suppl.,121, 580–590 (1928).

    CAS  Google Scholar 

  6. N. Bohr,Atomic Physics and Human Knowledge, Wiley, Chapman and Hall, New York, London (1958).

    Google Scholar 

  7. A. S. Pushkin,Complete Works, Vol. 2 [in Russian], Izd. Akad. Nauk SSSR, Moscow (1950).

    Google Scholar 

  8. P. Ya. Chaadaev,Complete Works and Selected Letters, Vol. 1 [in Russian], Nauka, Moscow (1991).

    Google Scholar 

  9. A. B. Migdal,Usp. Fiz. Nauk,147, 334 (1985).

    Google Scholar 

  10. L. A. Gribov, in:Modem Problems of Physical Chemistry [in Russian], Khimiya, Moscow (1987), pp. 211–262.

    Google Scholar 

  11. A. N. Tikhonov and V. Ya. Arsenin,Methods of Solving Ill-Posed Problems [in Russian], Moscow (1979).

  12. L. A. Gribov and V. I. Baranov,J. Mol. Struct.,224, 45–60 (1990).

    Article  CAS  Google Scholar 

  13. L. A. Gribov and A. I. Pavlyuchko,Opt. Spektrosk.,56, No. 6, 1015–1019 (1984).

    CAS  Google Scholar 

  14. M. V. Volkenshtein, L. A. Gribov, M. A. Elyashevich, et al.,Oscillation of Molecules [in Russian], Nauka, Moscow (1972).

    Google Scholar 

  15. L. A. Gribov and V. I. Baranov,Zh. Prikl. Spektrosk.,51, No. 6, 981–985 (1989).

    Google Scholar 

Download references

Authors

Additional information

Vernadskii Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences Translated fromZhurnal Strukturnoi Khimii, Vol. 35, No. 4, pp. 123–134, July–August, 1994.

Translated by O. Kharlamova

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gribov, L.A. Complementarity and justification in science, or comments on some fundamental concepts and problems in the theory and methods of structure and property investigations of complex molecules and molecular systems. J Struct Chem 35, 533–541 (1994). https://doi.org/10.1007/BF02578366

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02578366

Keywords

Navigation