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A correlation between the structure and some physical properties of binary molybdates (Tungstates) of uni- and bivalent metals

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Abstract

General principles of arrangement are discussed and analyzed for 13 known structural types (families) of binary molybdates and tungstates of uni-and bivalent metals, which were classified according to the degree of condensation of M2+On polyhedral and MoO4 tetrahedral constructions. The structural features of some phases correlate with their ferroelectric, ion-conducting, and luminescent (laser) properties. We suggest crystallochemical criteria and mechanisms of distortion (ferroelectric) phase transitions in palmierites, langbeinites, and Rb4Mn(MoO4)3 and show the paths of ionic transport in phases with NaCo231(MoO4)3, alluaudite, and Na2Mg5(MoO4)6 structures. On the basis of the analysis performed, we outlined the compounds that are the most promising for the development of inorganic materials with efficient physical properties.

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Authors
  1. S. F. Solodovnikov
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  2. R. F. Klevtsova
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  3. P. V. Klevtsov
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Additional information

Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 35, No. 6, pp. 145–157, November–December, 1994.

Translated by T. Yudanova

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Solodovnikov, S.F., Klevtsova, R.F. & Klevtsov, P.V. A correlation between the structure and some physical properties of binary molybdates (Tungstates) of uni- and bivalent metals. J Struct Chem 35, 879–889 (1994). https://doi.org/10.1007/BF02578121

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  • DOI: https://doi.org/10.1007/BF02578121

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