Skip to main content
SpringerLink
Log in

Synthesis, characterization, and x-ray structural study of binary lithium managanese(II) molybdate

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The binary molybdate of variable composition Li2−2nMn2+x(MoO4)3 (O<x<0.28 at 600°C), isostructural to Li2Fe2(MoO4)3, was discovered in the Li2MoO4-MnMoO4 system. We have grown single crystals of Li1.60Mn2.20(MoO4)3) and determined its crystal structure (space group Pnma, a=5.145, b=10.681, c=17.985 Å, Z=4). Along with statistical arrangement of Li and Mn in three different atomic positions, cation vacancies in one of these were found. Based on the data obtained, we propose to revise the compositions of some lithium-containing phases with the Li2Fe2(MoO4)3-type structure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C. Gicquel, M. Mayer, G. Perez, and R. Bouaziz,C. R. Acad. Sci.,C275, No. 4, 265–267 (1972).

    Google Scholar 

  2. V. A. Efremov and V. K. Trunov,Zh. Neorg. Khim.,17, No. 7, 2034–2039 (1972).

    CAS  Google Scholar 

  3. V. G. Penkova and P. V. Klevtsov, ——ibid.,22, No. 6, 1713–1715 (1977).

    CAS  Google Scholar 

  4. R. F. Klevtsova and S. A. Magarill,Kristallografiya,15, No. 4, 710–715 (1970).

    CAS  Google Scholar 

  5. M. Ozima, S. Sato, and T. Zoltai,Acta Crystallogr.,B33, No. 7, 2175–2181 (1977).

    CAS  Google Scholar 

  6. L. N. Demiyanets,Kristallografiya,14, No. 5, 955–958 (1969).

    Google Scholar 

  7. C. Gicquel-Mayer, M. Mayer, and G. Perez,C. R. Acad. Sci.,C289, No. 6, 181–183 (1979).

    Google Scholar 

  8. B. M. Wanklyn and F. R. Wondre,J. Mater. Sci.,11, No. 9, 1607–1614 (1976).

    Article  CAS  Google Scholar 

  9. G. M. Sheldrick,SHELX 76: Program for Crystal Structure Determination, Cambridge University, Cambridge (1976).

    Google Scholar 

  10. L. Katz, A. Kasenally, and L. Kihlborg,Acta Crystallogr.,B27, No. 11, 2071–2077 (1971).

    Google Scholar 

  11. I. D. Brown and D. Altermatt, ——ibid. B41, No. 4, 244–247 (1985).

    CAS  Google Scholar 

  12. S. C. Abrahams and J. M. Reddy,J. Chem. Phys.,43, No. 7, 2533–2543 (1965).

    Article  CAS  Google Scholar 

  13. A. Clearfield, A. Moini, and P. R. Rudolf,Inorg. Chem.,24, No. 26, 4606–4609 (1985).

    Article  CAS  Google Scholar 

  14. N. V. Belov, L. P. Otroshcheko, and V. I. Simonov,Kristallografiya,29, No. 1, 44–49 (1984).

    CAS  Google Scholar 

  15. V. K. Trunov, V. A. Efremov and Yu. A. Velikodnyi, inCrystal Chemistry and Properties of Binary Molybdates and Tungstates [in Russian], Nauka, Leningrad (1986), p. 76.

    Google Scholar 

  16. J. A. Ibers and G. W. Smith,Acta Crystallogr.,17, No. 2, 190–197 (1964).

    Article  CAS  Google Scholar 

  17. A. I. Korosteleva, V. I. Kovalenko, and E. A. Ukshe,Izv. Akad. Nauk SSSR, Neorg. Mater.,17, No. 4, 748–749 (1981).

    CAS  Google Scholar 

  18. V. A. Efremov and V. K. Trunov, ——ibid.,11, No. 2, 273–277 (1975).

    CAS  Google Scholar 

  19. V. A. Efremov, Yu. G. Petrosyan, and V. M. Zhukovskii,Zh. Neorg. Khim.,11, No. 1, 175–179 (1975).

    Google Scholar 

  20. T. Machej and J. Ziolkowski,J. Solid State Chem.,31, No. 2, 135–143 (1980).

    Article  CAS  Google Scholar 

  21. R. D. Shannon,Acta Crystallogr.,A32, No. 5, 751–767 (1976).

    CAS  Google Scholar 

  22. R. F. Klevtsova, A. A. Antonova, and L. A. Glinskaya,Kristallografiya,24, No. 5, 1043–1047 (1979).

    CAS  Google Scholar 

  23. J. M. Hughes, S. J. Starkey, M. L. Malinconico, and L. L. Malinconico,Am. Miner.,72, No. 9-10, 1000–1005 (1987).

    CAS  Google Scholar 

Download references

Authors
  1. S. F. Solodovinkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Z. A. Solodovnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. F. Klevtsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. A. Glinskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. P. V. Klevtsov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. E. S. Zolotova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 35, No. 6, pp. 136–144, November–December, 1994.

Translated by T. Yudanova

Rights and permissions

Reprints and permissions

About this article

Cite this article

Solodovinkov, S.F., Solodovnikova, Z.A., Klevtsova, R.F. et al. Synthesis, characterization, and x-ray structural study of binary lithium managanese(II) molybdate. J Struct Chem 35, 871–878 (1994). https://doi.org/10.1007/BF02578120

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02578120

Keywords

Search

Navigation