Skip to main content
SpringerLink
Log in

Crystal structure of [Mn(bpy)3](ClO4)2·0.5(bpy) (bpy=2,2′-bipyridine)

  • Note
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

A new monomeric manganese(II) complex with 2,2′-bipyridine (bpy), [Mn(bpy)3-] (ClO4)2·0.5(bpy), has been prepared and characterized by X-ray crystallography. The complex crystallizes in the triclinic space group\(P\bar 1\) witha=9.535(2),b=13.194(3),c=14.854(3) Å, α=96.50(3), β=107.26(3), γ=91.19(3)°,V=1770.2(7) Å3, andZ=2. The structure comprises discrete [Mn(bpy)3]2+ cations in which the metal atom is coordinated in a highly distorted octahedral environment by three chelate bpy ligands [Mn−N=2.229(3)–2.289(2) Å]. The solvate bpy molecule and a pair of coordinated bpy ligands each from the adjacent cations are arranged in an off-set fashion, showing significant intermolecular stacking interaction with close interplanar contacts ofca. 3.47 Å.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Chen, X.-M.; Tong, Y.-X.; Xu, Z.-T.; Mak, T.C.W.J. Chem. Soc. Dalton Trans. 1995, 4001.

  2. Chen, X.-M.; Wang, R.-Q.; Xu, Z.-T.Acta Crystallogr Sect. C 1995,51, 820.

    Article  Google Scholar 

  3. Chen, X.-M.; Wu, Y.-L.; Yang, Y.-S.Aust. J. Chem. 1996,48, 1643.

    Article  Google Scholar 

  4. Tong, M.-L.; Zhou, Z.-Y.; Wu, Y.-L.; Chen, X.-M.Mal. J. Sci. 1996,17B, in press.

  5. Sheldrick, G.M.SHELXTL-PC; User's Manual Sciemens Analytical X-ray Instruments, Inc., Madison, Wis, 1990.

    Google Scholar 

  6. Sheldrick, G.M.,SHELXL-93, Program for Crystal Structure Refinement University of Gottingen: Germany, 1993.

    Google Scholar 

  7. International Tables for X-ray Crystallography, Vol. C, Tables 4.2.6.8 and 6.1.1.4. Kluwer Academic Publisher: Dordrecht, 1992.

  8. Chen, X.-M.; Wang, R.-Q.; Yu, X.-L.Acta Crystallogr. Sect. C. 1995,51, 1545.

    Article  Google Scholar 

  9. Wada, A.; Katayama, C.; Tanaka,J. Acta Crystallogr. Sect. B 1976,32, 33194.

    Google Scholar 

  10. Yanagi, K.; Ohashi, Y.; Sasada, Y.; Kaizu, Y.; Kobayashi, H.Bull. Chem. Soc. Jpn. 1981,54, 118.

    Article  CAS  Google Scholar 

  11. Figgis, B.N.; Skelton, B.W.; White, A.H.Aust. J. Chem. 1978,31, 57.

    Article  CAS  Google Scholar 

  12. Hunter, C.A.; Sanders, J.K.M.J. Am. Chem. Soc. 1990,112, 5525.

    Article  CAS  Google Scholar 

  13. Chen, X.-M.; Tong, M.-L.; Luo, Y.-J.; Chen, Z.-N.Aust. J. Chem. 1996,49, 835.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Zhongshan University, 510275, Guangzhou, China

    Xiao-Lan Yu, Ye-Xiang Tong & Xiao-Ming Chen

  2. Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong

    Xiao-Lan Yu & Thomas C. W. Mak

Authors
  1. Xiao-Lan Yu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ye-Xiang Tong
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Xiao-Ming Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Thomas C. W. Mak
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yu, XL., Tong, YX., Chen, XM. et al. Crystal structure of [Mn(bpy)3](ClO4)2·0.5(bpy) (bpy=2,2′-bipyridine). J Chem Crystallogr 27, 441–444 (1997). https://doi.org/10.1007/BF02576481

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02576481

Key Words

Search

Navigation