Abstract
The crystal and molecular structure of the title complex, C18H19N2O2Ni, has been determined by direct methods. The compound crystallizes in the monoclinic crystal system witha=22.973(1),b=5.212(1),c=27.076(1)Å, β=106.46(1)°, space groupC2/c,V=3109.1(6)Å3, Z=8, andD x=1.51g cm−3. The nickel atom is in a slightly distorted square-planar environment of two oxygens [Ni(1)−O(1) 1.824(3) and Ni(1)−O(2) 1.856(3)Å] and two nitrogens [Ni(1)−N(1) 1.849(3) and Ni(1)−N(2) 1.932(3)Å] with O−Ni−N angles between 85.7(1) and 97.1(1)°. The nickel atom is 0.006 Å out of the plane of its ligands.
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Garnovskii, A.D.; Nivorozhkin, A.L.; Minkin, V.I.Coord. Chem. Rev. 1973,126, 1.
Maggio, F.; Pizzino, T.; Romano, V.Inorg. Chem. Lett. 1974,10, 1005.
Enraf-Nonius. CAD-4 Software 1993. Version 1.1. Delft. The Netherlands.
Sheldrick, G.M.Acta Crystallogr. 1990,A 46, 467.
Sheldrick, G.M., SHELXL-93: Program for the refinement of crystal structures. Univ. of Göttingen, Germany, 1993.
Kopfmann, G.; Huber, R.Acta Crystallogr. 1968,A 24, 348.
North, A.C.T.; Phillips, D.C.; Mathews, F.S.Acta Crystallogr. 1968,A 24, 351.
Fernandez-G, J.M.; Rosalez-Hoz, M.J.; Rubiyo-Arroyo, M.F.; Salcedo, R.; Toscano, R.A.; Vela, A.Inorg. Chem. 1987,26, 349.
Elerman, Y.; Paulus, H.; Svoboda, I.Z. Kristallogr. 1992,198, 132.
Johnson, C.K. ORTEP-II: Report ORNL-5138, Oak Ridge National Laboratory, Tennesse, USA,1976.
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Elerman, Y., Kabak, M. & Ülkü, D. Structure of (N-(2-hydroxyphenyl)-salicylaldiminopiperidino) Ni(II) complex. J Chem Crystallogr 27, 141–144 (1997). https://doi.org/10.1007/BF02575908
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DOI: https://doi.org/10.1007/BF02575908