Abstract
Ni(II) complexes with the composition [Ni(Ln)A] (n = 1-4, A = NH3, Py) based on the products obtained by the condensation of benzoylacetalaldehyde with hydrazides of aromatic acids (H2L1–H2L4) are synthesized and studied. The obtained crystallographic data for complex NiL2·Py are: triclinic crystal system, space group \(P\bar{1}\), a = 9.3151(9) Å, b = 10.5675(11) Å, c = 11.9266(7) Å, α = 112.030(7)°, β = 92.227(6)°, γ = 115.341(10)°, V = 955.33(17) Å3, Z = 2, R1 = 0.045, and wR2 = 0.106; for complex NiL4·NH3: monoclinic system, space group P21/c, a = 10.3837(9) Å, b = 8.2507(6) Å, c = 19.630(2) Å, β = 98.658(11)°, V = 1662.5(3) Å3, Z = 3, R1 = 0.0485, and wR2 = 0.1305.
Similar content being viewed by others
REFERENCES
K. C. Joshi, R. Bohra, and B. S. Joshi. Inorg. Chem., 1992, 4, 598 –603.
V. V. Pakal′nis, I. V. Zerova, S. I. Yakimovich, A. Yu. Ershov, and I. V. Lagoda. Russ. J. Org. Chem., 2009, 45(2), 285–291.
V. V. Alekseev, A. V. Zerov, V. A. Pakalnis, and S. I. Yakimovich. Abstracts: Tretya Vseross. Nauch. Konf. “Usp. Sintez. Kompleksoobr.” (Third All-Russia Sci. Conf. Int. Participation “Adv. Synth. Complex.”) [in Russian]. Moscow, Russia, April 21–25, 2014. RUDN: Moscow, 2014, 102.)
V. V. Alekseyev. Chem. Heterocycl. Compd., 2013, 49(3), 408–416.
E. A. Shokova, J. K. Kim, and V. V. Kovalev. Russ. J. Org. Chem., 2015, 51(6), 755–830.
V. V. Alekseev, S. I. Yakimovich, N. S. Guliy, A. V. Zerov, and A. Yu. Ershov. Tretya Vseross. Nauch. Konf. “Usp. Sintez. Kompleksoobr.” (Third All-Russia Sci. Conf. Int. Participation “Adv. Synth. Complex.”) [in Russian]. Moscow, Russia, April 21–25, 2014. RUDN: Moscow, 2014, 188.
K. G. Avezov, B. B. Umarov, S. A. Talipov, R. J. Kunafiev, and B. Y. Ibragimov. IUCrData, 2016, 3, 1–3.
M. A. Tursunov, K. G. Avezov, B. B. Umarov, and N. A. Parpiev. Russ. J. Coord. Chem., 2017, 43(4), 93–96.
M. A. Tursunov, B. B. Umarov, M. Ya., Ergashov, and K. G. Avezov. J. Struct. Chem., 2020, 61(1), 73–85.
M. A. Tursunov. Complexes of Some 3d Metals Based on Derivatives of Ketoaldehydes and Ketoesters, Their Structure and Properties: Ph.D. (Chem.) Dissertation. BukhSU: Bukhara, 2019.
B. B. Umarov, M. A. Tursunov, and V. V. Minin. Complex. Deriv. Ketoaldehydes Ketoesters. Nishon-noshir: Tashkent, 2016.
C. I. Someya, S. Inoue, E. Irran, and S. Enthaler. Inorg. Chem. Commun., 2014, 44, 114–118.
C. I. Someya, M. Weidauer, and S. Enthaler. Inorg. Chim. Acta, 2015, 434, 37–40.
N. A. Parpiev, B. B. Umarov, and K. G. Avezov. Perevat. Perfluoroalkyl β-Diketones and Their Complex. AOO Dizayn-Press: Tashkent, 2013.
O. V. Konnik, V. F. Shul′gin, E. A.Zamnius, A. N. Gusev, and V. V. Minin. Russ. J. Inorg. Chem., 2015, 60(5), 595–601.
A. Mukhopadhyay, G. Padmaja, Satyanarayan Pal, and Samudranil Pal. J. Organomet. Chem., 2012, 6(4), 381–386.
L. F. Tietze and T. Eicher. Reakt. Synth. Organ.-chem. Prakt. Forschungslab. Wiley-VCH, 1991.
L. N. Bazhenova. Kolich. Element. Analiz Organ. Soedin. (Quant. Elem. Anal. Org. Compd.) [in Russian]. Yekaterinburg, 2008.
B. N. Tarasevich, IK Spektr. Osnov. Klass. Organ. Soyed.: Sprav. Mater. (IR Spectra Princ. Clas. Org. Compd. Reference Materials) [in Russian]. MGU: Moscow, 2012.
A. A. Kazitsyna and N. B. Kupletskaya. Primeneniye UF-, IK- i YaMR-Spektr. Organ. Khim. (Appl. UV, IR NMR Spectr. Organic Chem.) [in Russian]. Kniga po Trebovaniyu: Moscow, 2013.
CrysAlisPro, Version 1.171.33.40. Oxford Diffraction, 2007.
G. M. Sheldrick. Acta Crystallogr., Sect. A, 2008, 64, 112–122.
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, and H. Puschmann. J. Appl. Crystallogr., 2009, 42, 339–341.
Kh. S. Gaybullayev, B. B. Umarov, N. A. Parpiyev, S. I. Yakimovich, and I. V. Zerova. Uzb. Khim. J., 1994, (3), 12–16.
A. Mukhopadhyay and S. Pal. Eur. J. Inorg. Chem., 2006, 2006(23), 4879–4887.
C. I. Someya, S. Inoue, S. Krackl, E. Irran, and S. Enthaler. Eur. J. Inorg. Chem., 2006, 2012(8), 1269–1277.
B. B. Umarov. Complex Compd. Some Trans. Metal. . bis-5-Hydroxypyrazolines. Ph.D. (Chem.) Dissertation. IU AN RUz.: Tashkent, 1996.
M. T. Toshev, V. G. Yusupov, Kh. B. Dustov, and N. A. Parpiev. Cryst. Chem. Metal Complex. Hydrazid. Hydrazon. Tashkent: Fan, 1994.
G. Sh. Karimova. Coord. Compd. Some 3d Metals Deriv. Benzoxazoline Quinazoline: Ph.D. Thesis. NUUz: Tashkent, 2012.
B. B. Umarov, M. T. Toshev, and S. O. Saidov. Koord. Khim., 1992, 18(9), 980–984.
B. B. Umarov, K. G. Avezov, M. A. Tursunov, N. G. Sevinchov, N. A. Parpiev, and G. G. Aleksandrov. Russ. J. Coord. Chem., 2014, 40(7), 473–476.
K. G. Avezov, S. I. Yakimovich, B. B. Umarov, V. V. Pakal′nis, G. G. Aleksandrov, T. N. Niyazkhanov, N. G. Sevinchov, and N. A. Parpiev. Russ. J. Coord. Chem., 2011, 37(4), 275–280.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflict of interests.
Additional information
Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 3, pp. 394-403.https://doi.org/10.26902/JSC_id69881
Rights and permissions
About this article
Cite this article
Tursunov, M.A., Umarov, B.B. & Avezov, K.G. SYNTHESIS AND CRYSTAL STRUCTURE OF NICKEL(II) COMPLEXES WITH BENZOYLACETALALDEHYDE DERIVATIVES. J Struct Chem 62, 369–378 (2021). https://doi.org/10.1134/S0022476621030033
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476621030033