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Structure determination of [tetraethylammonium]-[(1,3-dithiole-2-one-4,5-dithiolato)diphenyl-(thiocyanato-N)stannate]

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Abstract

The title compound (3) has been synthesised and its molecular structure has been elucidated by single crystal X-ray diffraction. Refinement of the complex in space groupP21/c witha=11.535(4),b=9.831(2),c=25.217(1) and β=94.23(5)° converged atR=0.064. The geometry at the tin center in the anion is trigonal bipyramidal, with the thiocyanato N atom and a dithiolato S atom in the axial sites. The tetraethylammonium cation exhibtis normal geometry.

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Authors and Affiliations

  1. Department of Chemistry, University of Aberdeen, Meston Walk, Old, AB9 2UE, Aberdeen, Scotland

    Zahid H. Chohan & James L. Wardell

  2. School of Pharmacy, The Robert Gordon University, Schoolhill, AB10 1FR, Aberdeen, Scotland

    Philip J. Cox

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  1. Zahid H. Chohan
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  2. Philip J. Cox
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  3. James L. Wardell
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Chohan, Z.H., Cox, P.J. & Wardell, J.L. Structure determination of [tetraethylammonium]-[(1,3-dithiole-2-one-4,5-dithiolato)diphenyl-(thiocyanato-N)stannate]. J Chem Crystallogr 27, 137–140 (1997). https://doi.org/10.1007/BF02575907

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  • DOI: https://doi.org/10.1007/BF02575907

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