Skip to main content
SpringerLink
Log in

Preparation, characterization and thermal stability of poly[2-(Dimethylamino)ethyl acrylate]

Polymer complexes of 2-(dimethylamino)ethyl acrylate with some transition metal chlorides

  • Published:
Journal of thermal analysis Aims and scope Submit manuscript

Abstract

Poly[2-(dimethylamino)ethyl acrylate] (PDAEA) and polymer complexes of 2-(dimethylamino)ethyl acrylate (DAEA) with nickel(II), copper(II), iron(III) and cobalt(II) chlorides were prepared and characterized by means of IR, electronic spectra and elemental analysis. The thermal stability of the homopolymer was compared with those of the polymer complexes, and the order of stability was given. The activation energies of the polymer complexes were calculated.

Zusammenfassung

Es wurden Poly(2-dimethyl-aminoethylacrylat) Homopolymer, PDAEA und Polymerkomplexe von 2-Dimethylaminoethylacrylat (DAEA) mit Nickel(II)-, Kupfer(II)-, Eisen(III)- und Kobalt(II)-chloriden hergestellt und mittels IR, Elektronenspektren und Elementaranalyse untersucht. Die thermische Stabilität des Homopolymers wurde mit der der Polymerkomplexe verglichen und eine Stabilitätsreihenfolge erstellt. Weiterhin wurden die Aktivierungsenergien für die Polymerkomplexe berechnet.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. Tazuke and S. Okamura, J. Polym. Sci., B5 (1967) 95.

    Article  CAS  Google Scholar 

  2. M. Imoto, T. Otsu and S. Shimizu, Makromol. Chem., 65 (1963) 174.

    Article  CAS  Google Scholar 

  3. S. Moita, M. Biswas and T. Uryu, Polym. Commun., 30 (1989) 252.

    Google Scholar 

  4. M. Biswas and S. Moitra, J. Appl. Polym. Sci., 38 (1989) 1243.

    Article  CAS  Google Scholar 

  5. M. A. Diab, A. Z. El-Sonbati, A. S. Hilali, H. M. Killa and M. M. Ghoniem, Polym. Deg. and Stab., 29 (1990) 165.

    Article  CAS  Google Scholar 

  6. A. Z. El-Sonbati and M. A. Diab, Acta Polymerica, 39 (1988) 124.

    Article  Google Scholar 

  7. A. M. El-Hendawy, A. Z. El-Sonbati and M. A. Diab, Acta Polymerica, 40 (1989) 710.

    Article  CAS  Google Scholar 

  8. W. M. Kulicke and H. Nottelmann Polym. Mat. Sci. Eng., 57 (1987) 265.

    CAS  Google Scholar 

  9. D. Hunkeler, Macromolecules, 24 (1991) 2160.

    Article  CAS  Google Scholar 

  10. J. Bassett, R. C. Denney, G. H. Jeffery and J. Mendham, Vogel's Textbook of Quant. Inorg. Analysis, Longman Group Limited, London, 1978, Chap. X.

    Google Scholar 

  11. K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, Wiley, New York, 1963.

    Google Scholar 

  12. N. S. Biradar and V. H. Kulkarni, J. Inorg. Nucl. Chem., 33 (1971) 3781.

    Article  CAS  Google Scholar 

  13. M. Pulaniandavor and C. Natarazon, Austr. J. Chem., 33 (1980) 737.

    Article  Google Scholar 

  14. E. Sawicki and T. W. Stanley, Chem. Analyst, 49 (1960) 49.

    Google Scholar 

  15. C. J. Ballhausen, Introduction to Ligand Field Theory, McGraw-Hill, New York, 1962, p. 253.

    Google Scholar 

  16. M. N. Patel and J. B. Patel, J. Macromol. Sci.-Chem., 19 (1983) 193.

    Article  Google Scholar 

  17. M. A. Diab, A. Z. El-Sonbati, A. A. El-Sanabari and F. I. Taha, Polym. Deg. and Stab., 23 (1988) 83.

    Article  Google Scholar 

  18. M. A. Diab, A. Z. El-Sonbati, A. A. El-Bindary and Y. A. Aggour, J. Thermal Anal. 36 (1990) 957.

    Article  CAS  Google Scholar 

  19. A. Z. El-Sonbati, A. El-Dissouky and M. A. Diab, Acta Polymerica, 40 (1989) 112.

    Article  CAS  Google Scholar 

  20. E. C. Winslow and A. A. Manning, J. Polym. Sci. A2 (1964) 4903.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Mansoura University, Faculty of Science, Chemistry Department, Demiatta, Egypt

    Y. A. Aggour

Authors
  1. Y. A. Aggour
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Aggour, Y.A. Preparation, characterization and thermal stability of poly[2-(Dimethylamino)ethyl acrylate]. Journal of Thermal Analysis 42, 1185–1191 (1994). https://doi.org/10.1007/BF02546928

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02546928

Keywords

Search

Navigation