Abstract
A mechanism is proposed for the reaction of aryl iodides with platinum(II) tetrachloride complexes in dimethylformamide including formation of PtCl3(CONMe2)2− in the first step through activation of a dimethylformamide C−H bond by platinum(II) and subsequent oxidative addition of ArI to this species.
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L. M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, 70 Lyuksemburg ul., Donetsk 340114, Ukraine. Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 34, No. 4, pp. 244–246, July–August, 1998.
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Bezbozhnaya, T.V., Litvinenko, S.L., Skripnik, S.Y. et al. Role of dimethylformamide in generating the active form of platinum for catalyzing the synthesis of diaryls from aryl iodides. Theor Exp Chem 34, 223–226 (1998). https://doi.org/10.1007/BF02523252
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DOI: https://doi.org/10.1007/BF02523252