Abstract
A rapid and specific method for the determination of131I in environmental water samples in the presence of some of the most important fission products is described. Radioiodine is separated from acidified water using tri-n-octylamine solution in toluene with dissolved iodine by one-stage static procedure with about 90% separation efficiency and 200-fold volume concentration. After the decolorization of the organic phase with NaOH in methanol, radioactivity of131I is counted by a toluene base liquid scintillator with a counting efficiency of 70%. The method is simple and enables to determine low radioactivity131I with a detection limit less than 5 pCi/1 in about 1.5 hrs.
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References
Environmental Aspects of Nuclear Power Stations (Proceedings Series), IAEA, Vienna, 1971.
Environmental Behaviour of Radionuclides Released in the Nuclear Industry (Proceedings Series), IAEA, Vienna, 1973.
J. TÖLGYESSY, Š. VARGA, Nuclear Analytical Chemistry, Vol. 3., University Park Press and Veda, Baltimore-Bratislava, 1974.
Rapid Methods for Measuring Radioactivity in the Environment (Proceedings Series), IAEA, Vienna, 1971.
V. M. VDOVENKO, Sovremennaya Radiokhimiya, Atomizdat, Moskva, 1969.
M. TSCHURLOVITS, H. BÖCK, Atomkernenergie, 23 (1974) 153.
Š. PALÁGYI, M. ZÁDUBAN, Radiochem. Radioanal. Letters, 20 (1974) 111.
Y. MARCUS, A. S. KERTES, Ion Exchange and Solvent Extraction of Metal Complexes, Wiley-Interscience, 1969.
J. INCZÉDY, Analytische Anwendungen von Ionenaustauschern, Akadémiai Kiadó, Budapest, 1964.
W. RIEMAN, H. F. WALTON, Ion Exchange in Analytical Chemistry, Pergamon, Oxford, 1970.
F. TERA, G. H. MORRISON, Anal. Chem., 38 (1966) 957.
S. F. PETERSON, F. TERA, G. H. MORRISON, J. Radioanal. Chem., 2 (1969) 115.
M. HEURTEBISE, W. J. ROSS, Anal. Chem., 43 (1971) 1438.
M. HEURTEBISE, W. J. ROSS, Anal. Chem., 44 (1972) 596.
V. S. SHMIDT, Ekstraktsiya Aminami, Atomizdat, Moskva, 1970.
R. DENIG, N. TRAUTMANN, G. HERRMANN, J. Radioanal. Chem., 5 (1970) 223.
K. UENO, A. SAITO, Anal. Chim. Acta, 56 (1971) 427.
S. IWAI, Y. INOUE, Y. TERASIMA, J. At. Energy Soc. Japan, 9 (1967) 249.
R. DENIG, N. TRAUTMANN, G. HERRMANN, J. Radioanal. Chem., 6 (1970) 331.
F. E. BUTLER, A. R. BOULOGNE, E. A. WHITLEY, Health Physics, 12 (1966) 927.
S. OHNO, Analyst, 96 (1971) 423.
R. FOSTER, Organic Charge-Transfer Complexes, Academic Press, London, 1969.
K. HÖLL, Water, Examination, Assessment, Conditioning, Chemistry, Bacteriology, Biology, Walter de Gruyter, Berlin, 1972.
M. ZADUBAN, N. STOLLÁROVÁ, Š. PALÁGYI, Radiochem. Radioanal. Letters, 3 (1970) 129.
J. J. GABAY, C. J. PAPERIELLO, S. GOODYEAR, J. C. DALY, J. M. MATUSZEK, Health Physics, 26 (1974) 89.
W. W. FLYNN, Anal. Chim. Acta, 76 (1975) 113.
T. GROENEWALD, Anal. Chem., 43 (1971) 1678.
J. H. HARLEY (Ed), HASL Procedures Manual, U. S. Energy Research and Development Administration, New York, 1972.
ICRP Report of Committee II on Permissible Dose for Internal Radiation, 1959.
WHO, Technical Report Series 173, 1959.
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Palágyi, Š. Rapid determination of131I in environmental waters using a liquid anion exchanger. J. Radioanal. Chem. 29, 271–285 (1976). https://doi.org/10.1007/BF02520759
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DOI: https://doi.org/10.1007/BF02520759