Abstract
The chemical state of the products of99TcO −4 reduction by Sn(II) in citrate media has been investigated using electrochemical methods. The Tc(V) chelates formed after consumption of one mole Sn(II)/g-atom TcO −4 were identified as oxo(biscitrato)technetates(V) existing in different coordination isomers. Their reduction products were hydroxo (biscitrato)technetates(IV). The products proved to be the same as reported in the case of the electrochemical reduction of TcO −4 in citric acid.
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Muenze, R., Hoffmann, I., Dreyer, R. et al. Characterization of the reduction products of99TcO −4 with stannous ions in citrate solutions. J. Radioanal. Chem. 74, 63–72 (1982). https://doi.org/10.1007/BF02520359
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DOI: https://doi.org/10.1007/BF02520359