Abstract
The substoichiometric separation of lanthanum was studied on the system EDTA —lanthanum—8-hydroxyquinoline. The optimum conditions for the substoichiometric separation of lanthanum were calculated theoretically and these results were examined experimentally. By using the two chelating agents, EDTA and 8-hydroxyquinoline, lanthanum could be separated substoichiometrically with good accuracy and precision. This method was applied to the determination of lanthanum by activation analysis, and found to be available for the determination of trace amount of lanthanum.
Similar content being viewed by others
References
G. N. BILIMOVICH, V. V. ATRASHKEVICH, I. P. ALIMARIN; J. Anal. Chem. USSR., 29 (1974) 555.
G. B. BRISCOE, A. DODSON, Talanta, 14 (1967) 1051.
M. KATOH, K. KUDO, Bunseki Kagaku, 32 (1983) 1.
L. D. AKOL'ZINA, G. N. BILIMOVICH, I. P. ALIMARIN, N. N. CHURKINA, J. Anal. Chem. USSR., 30 (1975) 1467.
NBS Certificate of Analysis for Orchard Leaves (SRM-1571), August 31, 1977.
L. G. SILLÉN, A. E. MARTEL, Stability Constants of Metal-Ion Complexes, Suppl. No. 1, Spec. Publ., No. 25. The Chemical Society, London, 1971.
D. DYRSSEN, Svensk. kem. tidskr., 66 (1954) 234.
E. S. GLADNEY, Anal. Chim. Acta, 118 (1980) 385.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Katoh, M., Kudo, K. Substoichiometric determination of lanthanum by using EDTA and 8-hydroxyquinoline. J. Radioanal. Chem. 79, 23–34 (1983). https://doi.org/10.1007/BF02518847
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02518847