Abstract
A rapid method has been developed for the determination of tungsten, especially in rocks. The reaction182W(n, γ)183mW (T=5.3 sec), with a thermal neutron capture cross-section of 0.5 b was used. The samples were irradiated in the fast pneumatic system of the FRM, which is described briefly. The low-energy γ-rays of the isomer183mW were measured by a high-resolving Ge(Li) detector. The sensitivity of the method is 0.1 mg tungsten with an accuracy of about 5%; the minimum concentration is 0.1–0.2% W in geological samples. The analysis time is 2 min per sample.
Similar content being viewed by others
References
R. Bachman, C. Banks, Anal. Chem., 41 (1969) 135 R.
R. Bachman, C. Banks, Anal. Chem., 43 (1971) 120 R.
H. Hamaguchi, R. Kuroda, T. Shimizu, I. Tsjkaha, R. Yamamoto, Geochim. Cosmochim. Acta, 27 (1962) 503.
A. Amirudin, W. D. Ehman, Geochim. Cosmochim. Acta, 26 (1962) 1011.
D. H. F. Atkins, A. A. Smales, Anal. Chim. Acta, 22 (1960) 462.
H. H. Kramer, U. J. Molinski, R. S. Tilburg, W. H. Wahl, P. M. Stier, NYO-10174, 1963.
R. Coulomb, J. C. Schilitz, Radiochemical Methods of Analysis, Vol. 2, IAEA, Vienna, 1965, p. 177.
Deutsche Metallgesellschaft Frankfurt, private communication.
H. Stärk, Techn. Universität München, internal report.
U. Fanger, D. Heck, P. Martens, R. Pepelnik, H. Schmidt, KFK 1404, 1971.
O. U. Anders, Anal. Chem., 33 (1961) 1706.
J. Janczyszyn, L. Loska, L. Górski, Radiochem. Radioanal. Letters, 8 (1971) 363.
G. V. Leushkina, E. M. Lobanov, A. G. Dutov, N. P. Matveeva, At. Energ. (USSR), 35 (1969) 381.
G. V. Leushkina, E. M. Lobanov, A. G. Dutov, N. P. Matveeva, Zavodsk. Lab., 35 (1969) 715.
Nuklidkarte BMBW, 3. Auflage 1968.
I. M. Y. Pagden, G. J. Person, J. M. Bewers, J. Radioanal. Chem., 8 (1971) 373.
C. M. Lederer, I. M. Hollander, I. Perlman, Table of Isotopes, 6th ed., Wiley, New York, 1967.
A. Z. Nagy, A. Csőke, E. Szabó, KFKI-70-18 NAC, Budapest.
R. Henkelmann, D. C. Aumann, H.-J. Born, Z. Anal. Chem., 233 (1969) 1.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Zinner, H., Henkelmann, R. & Stärk, H. Rapid determination of tungsten in rocks using183mW. J. Radioanal. Chem. 16, 31–38 (1973). https://doi.org/10.1007/BF02517849
Issue Date:
DOI: https://doi.org/10.1007/BF02517849