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Substitution kinetics of chelate complexes as studied by isotopic exchange

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Abstract

The fact that isotopic exchange reactions take place at chemical equilibirum makes this type of reaction useful for kinetic studies. In the case of chelate complexes [M(chel)n] isotopic exchange reactions can be classified as metal exchange reactions. [M(chel)n]+*M⇆[*M(chel)n]+M and ligand exchange reactions [M(chel)n]+*chel⇆[M(chel)n−1 *chel]+chel The literature on type (a) and type (b) reactions of mainly transition metal complexes is reviewed with respect to the kinetic information obtained. The value and the limitations of isotopic exchange studies as a kinetic technique are discussed.

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  1. Anorganische Chemie III, Eduard-Zintl-Institut, Technische Hochschule Darmstadt, 61, Darmstadt, (FRG)

    H. Elias

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Elias, H. Substitution kinetics of chelate complexes as studied by isotopic exchange. J. Radioanal. Chem. 30, 25–34 (1976). https://doi.org/10.1007/BF02516616

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