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Chromatographic behaviour of a number of metal ions on DEAE-cellulose layers in thiosulfate media

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Abstract

The adsorption behavior of 47 metal ions on DEAE-cellulose (Cl−) has been surveyed in aqueous thiosulfate solution by thin-layer chromatographic technique. The Rf values are measured as a function of thiosulfate concentration (0.010–2.0M) and are compared with those obtained on a microcrystalline cellulose Avicel SF. Generally, the ion-exchange adsorption of metal ions are weak or moderate over the thiosulfate concentration range tested except for a few metal ions like Mo(VI), Sb(III), Bi(III) etc., which have high preference to DEAE-cellulose. A variety of chromatographic distribution exhibited by metal ions allows to develop a number of separations of analytical and radiochemical interest.

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Authors and Affiliations

  1. Laboratory for Analytical Chemistry, Faculty of Engineering, University of Chiba, Yayoi-cho, Chiba, (Japan)

    R. Kuroda, H. Matusue & K. Oguma

Authors
  1. R. Kuroda
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  2. H. Matusue
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  3. K. Oguma
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Kuroda, R., Matusue, H. & Oguma, K. Chromatographic behaviour of a number of metal ions on DEAE-cellulose layers in thiosulfate media. J. Radioanal. Chem. 36, 119–124 (1977). https://doi.org/10.1007/BF02516259

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  • DOI: https://doi.org/10.1007/BF02516259

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