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Solvent extraction of technetium(VII) by 4-(5-nonyl)pyridine and its separation from uranium and some fission products

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Abstract

The extraction of technetium (VII) by 4-(5-nonyl)pyridine has been investigated from different aqueous solutions. Separation from uranium and some fission products has been achieved in nitrate media. From the results of partition experiments, attempts have been made to deduce the nature of the extracted species.

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References

  1. G. E. Boyd, Q. V. Larsen, E. E. Motta, Rept., AECD-2151, June 1948; Rept., ORNL-2159 and ORNL-2584, 1958.

  2. S. Tribalat, J. Beydon, Anal. Chim. Acta, 6 (1952) 96.

    Article  CAS  Google Scholar 

  3. M. S. Faddeeva, O. N. Panlov, V. V. Bakunina, Zh. Neorg. Khim., 3 (1958) 165.

    Google Scholar 

  4. J. B. Gerlit, Proc. Intern. Conf. Peaceful Uses of Atomic Energy, Geneva 1955, 7 (1956) 145.

    CAS  Google Scholar 

  5. T. Kiba, A. Miura, Y. Sugioka, Bull. Chem. Soc. Japan, 36 (1963) 663.

    Article  CAS  Google Scholar 

  6. E. Anders, The Radiochemistry of Technetium, AEC NAS-NS, Rept. No. 3021 (1960).

  7. G. B. S. Salaria, C. L. Rulfs, P. J. Elving, Anal. Chem., 35 (1963) 983.

    Article  CAS  Google Scholar 

  8. S. J. Rimshav, G. F. Malling, Anal. Chem. 33 (1961) 751.

    Article  Google Scholar 

  9. N. H. Canbell, Anal. Chem., 35 (1963) 2052.

    Article  Google Scholar 

  10. A. A. Pozdnyakov, Usp. Khim., 34 (1965) 300.

    CAS  Google Scholar 

  11. R. J. Meyer, R. D. Oldham, R. P. Larsen, Anal. Chem., 36 (1964) 1975.

    Article  CAS  Google Scholar 

  12. G. Goldstein, J. A. Dean, Radiochim. Acta, 5 (1966) 18.

    CAS  Google Scholar 

  13. A. S. Solovkin, M. I. Konarev, D. P. Adalv, Zh. Neorg. Khim., 5 (1960) 1861.

    CAS  Google Scholar 

  14. R. Colton, R. D. Peacock, Q. Rev. Chem. Soc., 16 (1962) 299.

    Article  CAS  Google Scholar 

  15. J. J. Buther, R. M. Diamond, J. Phys. Chem., 73 (1969) 675.

    Article  Google Scholar 

  16. T. J. Conocchiobi, M. I. Tocher, R. M. Diamond, J. Phys. Chem., 69 (1965) 1106.

    Google Scholar 

  17. A. S. Kertes, A. Beck, J. Chem. Soc., (1961) 1922.

  18. A. V. Petrov, A. V. Karyakin, K. V. Marunova, Zh. Neorg. Khim., 10 (1965) 986.

    CAS  Google Scholar 

  19. J. Spitsyn, A. Vikta, A. F. Kuzin, N. N. Zamoshnikova, T. S. Togil, Dokl. Akad. Nauk, SSSR, 144 (1962) 1066.

    CAS  Google Scholar 

  20. A. N. Zelinkman, L. Dregan, Zh. Neorg. Khim., 12 (1967) 261.

    Google Scholar 

  21. L. J. Anokhina, N. A. Agrinskaya, V. I. Petrashen, Russ. J. Inorg. Chem., 15 (1970) 78.

    Google Scholar 

  22. A. A. Zaitsev, I. A. Lebedev, S. V. Pirozhkov, G. N. Takovlev, Russ. J. Inorg. Chem., 8 (1963) 1260.

    Google Scholar 

  23. R. N. Maslova, V. V. Fomin, Zh. Neorg. Khim., 6 (1961) 738.

    CAS  Google Scholar 

  24. V. V. Fomin, R. N. Maslova, Zh. Neorg. Khim., 6 (1961) 481.

    CAS  Google Scholar 

  25. A. K. Babko, B. I. Nabivanets, Zh. Neorg. Khim., 2 (1975) 2085.

    Google Scholar 

  26. E. N. Gilbert, V. A. Pronin, I. M. Ivanov, S. N. Ivanova, A. A. Vasileva, P. I. Artyukhin, L. M. Gindin, Zh. Neorg. Khim., 13 (1968) 1055.

    CAS  Google Scholar 

  27. V. M. Vdovenko, A. A. Lipovskii, M. G. Kuzina, Radiokhimiya, 3 (1961) 555.

    CAS  Google Scholar 

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Iqbal, M., Ejaz, M. Solvent extraction of technetium(VII) by 4-(5-nonyl)pyridine and its separation from uranium and some fission products. J. Radioanal. Chem. 23, 51–62 (1974). https://doi.org/10.1007/BF02514344

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  • DOI: https://doi.org/10.1007/BF02514344

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