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The α-effect of oximate ions and solvent effect in the transfer of the toluenesulfonyl group in aqueous dimethylsulfoxide

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Abstract

The kinetic behaviour of oximate ions was studied in the transfer of the toluenesulfonyl group in aqueous dimethylsulfoxide (0–95 vol.% DMSO). The solvation effects of the solvent are a factor controlling the nucleophilicity and magnitude of the α-effect of the oximate ions.

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Authors
  1. Yu. S. Simanenko
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  2. T. M. Zubareva
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  3. I. P. Suprun
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  4. T. M. Prokop'eva
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  5. A. F. Popov
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  6. E. A. Karpichev
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Additional information

L. M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, 70 R. Lyuksemburg ul., Donetsk 340114, Ukraine. Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 36, No. 1, pp. 30–35, January–February, 2000.

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Simanenko, Y.S., Zubareva, T.M., Suprun, I.P. et al. The α-effect of oximate ions and solvent effect in the transfer of the toluenesulfonyl group in aqueous dimethylsulfoxide. Theor Exp Chem 36, 31–36 (2000). https://doi.org/10.1007/BF02511533

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  • DOI: https://doi.org/10.1007/BF02511533

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