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Structure-reactivity cross correlations in nucleophilic substitution: Isoparametricity and transition-state structure

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Abstract

Data are surveyed on cross correlations for nucleophilic substitution at benzoyl, benzyl, and benzhydryl carbon atoms. The cross correlation coefficients and isoparametric points are used to interpret the reaction mechanisms.

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  1. I. V. Shpan'ko
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Donetsk State University, 24 Universitetskaya ul., Donetsk 340055, Ukraine. Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 35, No. 2, pp. 67–78, March–April, 1999.

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Shpan'ko, I.V. Structure-reactivity cross correlations in nucleophilic substitution: Isoparametricity and transition-state structure. Theor Exp Chem 35, 63–74 (1999). https://doi.org/10.1007/BF02511491

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  • DOI: https://doi.org/10.1007/BF02511491

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