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Effect of rehydration on the porosity of MCM-41 mesoporous molecular sieves

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Abstract

In distinction from aluminosilicates, the porosity of the detemplated silicous MCM-41 is significantly reduced after several cycles of dehydration-rehydration. The stability of Si-MCM-41 is not changed by absorption-desorption of nonpolar hexane. An explanation is proposed for the effect of rehydration on the porosity of MCM-41.

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References

  1. A. Corma,Chem. Rev.,97, 2373–2419 (1997).

    Article  CAS  Google Scholar 

  2. A. S. Kovalenko, A. S. Ilyn, and A. P. Fillipov,Teor. Éksp. Khim.,33, No. 5, 322–337 (1997).

    Google Scholar 

  3. J. S. Beck, J. C. Vartuli, W. J. Roth, et al.,J. Am. Chem. Soc.,114, No. 27, 10834–10843 (1992).

    Article  CAS  Google Scholar 

  4. B. M. Mitsyuk and L. I. Gorogotskaya,Physicochemical Conversions of Silica under Metamorphism Conditions [in Russian], Naukova Dumka, Kiev (1980).

    Google Scholar 

  5. N. Constel, F. Di Renzo, and F. Fajula,J. Chem. Soc., Chem. Commun., No. 8, 967–968 (1994).

    Google Scholar 

  6. Z. Luan, Chi-Feng Cheng, W. Zhou, and J. Klinowski,J. Phys. Chem.,99, No. 3, 1018–1024 (1995).

    Article  CAS  Google Scholar 

  7. D. Brek,Zeolitic Molecular Sieves [Russian translation], Mir, Moscow (1976).

    Google Scholar 

  8. V. A. Astakhov, M. M. Dubinin, and P. G. Romankov,Adsorbents, Their Preparation, Properties and Uses, Nauka, Leningrad (1971), pp. 92–97.

    Google Scholar 

  9. Ji Man Kim, Ja Hun Kwak, Shinae Jun, and Roo Ryong,J. Phys. Chem.,99, No. 45, 16742–16747 (1995).

    Article  CAS  Google Scholar 

  10. I. E. Neimark and R. Yu. Sheinfain,Silicagel, Its Preparation, Properties and Uses [in Russian], Naukova Dumka, Kiev (1973).

    Google Scholar 

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Authors
  1. F. M. Bobonich
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  2. Yu. G. Voloshina
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  3. L. A. Matkovskaya
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  4. V. N. Solomakha
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  5. Yu. G. Gol’tsov
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Additional information

L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Prospekt Nauki, Kiev 252039, Ukraine. Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 35, No. 1, pp. 50–55, January–February, 1999.

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Bobonich, F.M., Voloshina, Y.G., Matkovskaya, L.A. et al. Effect of rehydration on the porosity of MCM-41 mesoporous molecular sieves. Theor Exp Chem 35, 52–56 (1999). https://doi.org/10.1007/BF02511128

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  • DOI: https://doi.org/10.1007/BF02511128

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