Abstract
Changes in the isotopic composition of electrolyte lithium are studied experimentally when thin-film titanium-aluminum systems are enriched in hydrogen. Strong deviations of the lithium isotope concentration from their natural abundances are observed both in the surface titanium layer and at the titanium-aluminum interface. Analysis of the experimental results permits us to conclude that isotope-induced transformations occur in materials enriched in hydrogen due to cold diffusion of impurity atoms stimulated by hydrogen migration and non-equilibrium chemical reactions.
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References
I. P. Chernov, N. N. Nikitenkov, L. N. Puchkareva,et al., Izv. Vyssh. Uchebn. Zaved., Fizika, No. 4, 61–65 (1999).
H. Gnaser and I. D. Hutcheon, Sur. Sci.,195, 499 (1988).
S. A. Shwarz, J. Vac. Sci. Technol., A5(3), May/June 544 (1987).
H. Gnaser and H. Oechsner, Nucl. Instrum. Methods, B48, 544 (1990).
I. Prigogine and I. Stegners, Order out of Chaos [Russian translation], Progress, Moscow (1986).
A. A. Samarskii (ed.) Computers, Models, and Simulation Experiment [in Russian], Nauka, Moscow (1988).
Computers and Nonlinear Phenomena [in Russian], A. A. Samarskii (ed.), Nauka, Moscow (1988).
G. Careri, Order and Disorder in Matter [Russian translation], Mir, Moscow (1985).
J. W. Rich and R. C. Bergman, in Capitelli (ed)., Non-equilibrium Vibrational Kinetics [Russian translation], Mir, Moscow (1989).
Additional information
Tomsk Polytechnical University and Fraunhofer Institute for Non-Destructive Testing, Germany. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 29–33, November 1999.
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Chernov, I.P., Nikitenkov, N.N., Kröning, M. et al. Changes in lithium isotopic composition in hydrogen-enriched Ti/Al systems. Russ Phys J 42, 947–951 (1999). https://doi.org/10.1007/BF02509687
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DOI: https://doi.org/10.1007/BF02509687