Abstract
In the framework of the Mc Millan-Mayer theory, the enthalpy, volume, and heat capacity coefficients of binary and ternary interactions of amides, alcohols, and acetonitrile in water and nonaqueous solvents were obtained at various temperatures. No pronounced regularities in changes in the coefficients of multiple interactions observed in aquous solutions were found for nonaqueous solutions of the substances studied. None of the considered coefficients can be used as a criterion for solvophobicity.
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References
Yu. M. Kessler and A. L. Zaitsev,Sol'vofoobnye effekty. Teoriya, eksperiment, praktika [Solvophobic Effects. Theory, Experiment, Practice], Khimiya, Leningrad, 1989, 312 pp. (in Russian)
W. G. McMillan and J. E. Mayer,J. Chem. Phys., 1945,13, 276.
J. G. Kikwood and F. P. Buff,J. Chem. Phys., 1951,19, 774.
Yu. M. Kessler, inSovremennee problemy khimii rastvorov [Modern Problems of Solution Chemistry], Nauka, Moscow, 1986, 63 (in Russian).
V. K. Abrosimov,Zh. Khim. Termodin. i. Termokhim. [J. Chem. Thermodynamics and Thermochemistry], 1992,2, 159 (in Russian).
Yu. M. Kessler and N. A. Abakumova,Izv. Vuzov Khim. Khim. Tekhnol. [Bull. High. Educt. Inst., Chem. Chem. Technol.], 1992,25, 162 (in Russian).
F. Franks and B. Watson,Trans. Faraday Soc., 1967,63, 329.
A. C. Rouw and G. Somsen,J. Chem. Thermodyn., 1981,13, 67.
I. R. Tasker and R. H. Wood,J. Phy. Chem., 1982,86, 4040.
H. L. Friedman and C. V. Krishnan,J. Solut. Chem., 1973,2, 119.
J. E. Mayrath and R. H. Wood,J. Chem. Thermodyn., 1983,15, 625.
G. Roux, D. Roberts, G. Perron, and J. E. Desnoyers,J. Solut. Chem., 1980,9, 305.
C. Jolicoeur and G. Lacroix,Can. J. Chem. 1976,54, 624.
C. de Visser, G. Perron, and J. E. Desnoyers,Can. J. Chem., 1977,55, 856.
C. de Visser, P. Pel, and G. Somsen,J. Solut. Chem., 1977,6, 571.
V. P. Belousov, and M. Yu. Panov,Termodinamika vodnykh rastvorov neelektrolitov [Thermodynamics of Aqueous Solutions of Nonelectrolytes], Khimiya, Leningard, 1983, 159 pp. (in Russian).
M. V. Kulikov, A. M. Kolker, L. P. Safonova, and Al. G. Krestov,Izv. Akad. Nauk SSSR, Ser. Khim., 1990, 2532 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990,39, 2289 (Engl. Transl.)].
S. K. Suri, J. J. Spitzer, R. H. Wood, E. G. Abel, and P. T. Thompson,J. Solut. Chem., 1985,14, 781.
O. Kiyohara, G. Perron, and J. E. Desnoyers,Can. J. Chem., 1975,53, 3263.
A. M. Zaichikov and G. A. Krestov,Zh. Fiz. Khim., 1995,69, 389 [Russ. J. Phys. Chem., 1995,69, (Engl. Transl.)].
A. M. Zaichikov and Yu. G. Bushuev,Zh. Fiz. Khim., 1995,69, 1942 [Russ. J. Phys. Chem., 1969 (Engl. Transl.)].
A. M. Zaichikov and O. E. Golubinskii,Zh. Fiz. Khim., 1996,70, 1175 [Russ. J. Phys. Chem., 1986,70 (Engl. Transl.)].
H. C. Zegers and G. Somsen,Abstras. IUPAC Conf. Chem. Thermodyn., Univ. College, London, 1982, 5. 31.
M. Bloemendal and G. Somsen,Abstrs. IUPAC Conf. Chem. Thermodyn., Univ. College, London, 1982, 7.3.
G. D. Craft and R. H. Wood,J. Solut. Chem., 1977,6, 525.
L. Piikkarainen,Thermochim. Acta, 1991,178, 311.
M. Bloemendal, A. C. Rouw, and G. Somsen,J. Chem. Soc., Faraday Trans., 1986,82, 53.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1587–1591, September, 1997.
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Kulikov, M.V., Zaichikov, A.M. Solvophobic effects in binary nonaqueous mixtures. Russ Chem Bull 46, 1513–1517 (1997). https://doi.org/10.1007/BF02502930
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DOI: https://doi.org/10.1007/BF02502930