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Metallation of the methyl group ino-nitrosotoluene: synthesis and the molecular structure of the binuclear complex [o-(NO)(CH2)C6H4)]2Pd2(μ-OOCCF3)2

  • Organometallic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The reaction of the tetranuclear cluster Pd4(CO)4(OOCCF3)4 witho-nitrosotoluene afforded the Pd11-containing complex [o-(NO)(CH2)C6H4]2Pd2(μ-OOCCF3)2. The elimination of CO2 and the formation of organic products of transformation of tolylnitrene species (azotoluene, ditolylamine, and tolylisocyanate) were observed in the course of the reaction. The title complex was characterized by IR and1H NMR spectroscopy. Its structure was established by X-ray diffraction analysis. It was suggested that the reaction proceeds through intermediate formation of nitrene complexes.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation

    T. A. Stromnova, S. T. Orlova, D. N. Kazyul'kin, I. P. Stolyarov & I. L. Eremenko

Authors
  1. T. A. Stromnova
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  2. S. T. Orlova
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  3. D. N. Kazyul'kin
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  4. I. P. Stolyarov
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  5. I. L. Eremenko
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 147–150, January, 2000.

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Stromnova, T.A., Orlova, S.T., Kazyul'kin, D.N. et al. Metallation of the methyl group ino-nitrosotoluene: synthesis and the molecular structure of the binuclear complex [o-(NO)(CH2)C6H4)]2Pd2(μ-OOCCF3)2 . Russ Chem Bull 49, 150–153 (2000). https://doi.org/10.1007/BF02499082

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  • DOI: https://doi.org/10.1007/BF02499082

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