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Thermochemistry of heteroatomic compounds

17. Theoretical calculations of vaporization enthalpies for alkylphosphines and alkyl(aryl)phosphines

  • Physical Chemistry
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Abstract

The vaporization enthalpies (ΔH vap) of 97 primary, secondary, and tertiary alkylphosphines and alkyl(aryl)phosphines with different spatial structures were calculated using the Trouton and Wadso equations and the first-order topological solvation index1χs. The contributions of the H2P and HP groups and the phosphorus atom to the vaporization enthalpies of primary, secondary, and tertiary phosphines, respectively, were calculated. The results obtained can be used in calculations of ΔH vap for related phosphorus compounds.

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Authors and Affiliations

  1. Kazan State Academy of Construction and Architecture, 1 ul. Zelyonaya, 420043, Kazan, Russian Federation

    V. V. Ovchinnikov, L. R. Khazieva & L. I. Lapteva

  2. Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    V. V. Ovchinnikov & A. I. Konovalov

Authors
  1. V. V. Ovchinnikov
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  2. L. R. Khazieva
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  3. L. I. Lapteva
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  4. A. I. Konovalov
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Additional information

For Part 16, see Ref. 1.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 32–37, January, 2000.

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Ovchinnikov, V.V., Khazieva, L.R., Lapteva, L.I. et al. Thermochemistry of heteroatomic compounds. Russ Chem Bull 49, 33–38 (2000). https://doi.org/10.1007/BF02499061

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  • DOI: https://doi.org/10.1007/BF02499061

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