Skip to main content
SpringerLink
Log in

Unusual rearrangement of the Ru3(μ-CO)2(CO)6{μ3-η1:η1:η4:η4-C4Ph2(CH=CHPh)2} complex containing an open triruthenium framework to the Ru3-triangular cluster Ru3(CO)8{μ3-η1:η1:η4:η2-C4Ph2(CH=CHPh)2}. Reactions of Ru3(CO)8{μ3-η1:η1:η4:η2-C4Ph2(CH=CHPh)2} with PPh3, P(OPri)3, CO, and the crystal structure of Ru3(CO)8(PPh3{μ-η1:η1:η4-C4Ph2(CH=CHPh)2}

  • Organometallic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Complex Ru3(μ-CO)2(CO)6{μ3-η1:η1:η4:η4-C4Ph2(CH=CHPh)2} containing an open triruthenium framework undergoes rearrangement to the Ru3-triangular Ru3(CO)8{μ3-η1:η1:η4:η2-C4Ph2(CH=CHPh)2) cluster when heated in refluxing hexane. Reactions of the latter complex with PPh3, P(OPri)3, and CO were studied. The structure of one of the reaction products, the Ru3(CO)8(PPh3{μ3-η1:η1:η4-C4Ph2(CH=CHPh)2} cluster, was established by X-ray structural analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. A. Koridze, V. I. Zdanovich, N. V. Andrievskaya, Yu. Siromakhova, P. V. Petrovskii, M. G. Ezernitskaya, F. M. Dolgushin, A. I. Yanovsky, and Yu. T. Struchkov,Izv. Akad. Nauk, Ser. Khim., 1996, 1261 [Russ. Chem. Bull., 1996,45, 1200 (Engl. Transl.)].

    Google Scholar 

  2. W. B. Faklhammer and H. Stolzenberg, inComprehensive Organometallic Chemistry, Eds. G. Wilkinson, F. G. A. Stone, and E. Abel, Pergamon Press, Oxford, 1982, Ch. 31.4.

    Google Scholar 

  3. R. P. Dodge and V. Schomaker,J. Organomet. Chem., 1965,3, 274.

    Article  CAS  Google Scholar 

  4. G. Cetini, O. Gambino, E. Sappa, and M. Valle,J. Organomet. Chem., 1969,17, 437.

    Article  CAS  Google Scholar 

  5. S. Rivomonana, G. Lavigne, N. Lugan, and J. -J. Bonnet,Organometallics, 1991,10, 2285.

    Article  Google Scholar 

  6. E. Rosenberg, S. Aime, L. Milone, E. Sappa, A. Tiripicchio, and A. M. Manotti Lanfredi,J. Chem. Soc., Dalton Trans., 1981, 2023.

  7. K. Onitsuka, K. Miygi, T. Adachi, T. Yoshida, and K. Sonogashira,Chem. Lett., 1994, 2279.

  8. L. J. Todd, J. P. Hickey, J. K. Wilkinson, J. C. Huffman, and K. Folting,J. Organomet. Chem., 1976,112, 167.

    Article  CAS  Google Scholar 

  9. R. Benfield, B. F. G. Johnson, P. Raithby, and G. M. Sheldrick,Acta Crystallogr., 1978,B34, 666.

    CAS  Google Scholar 

  10. G. Lavigne, N. Lugan, and J. -J. Bonnet,Acta Crystallogr., 1982,B38, 1911.

    CAS  Google Scholar 

  11. D. H. Farrar, A. J. Poë, and Y. ZhangJ. Am. Chem. Soc., 1994,116, 6252.

    Article  CAS  Google Scholar 

  12. A. J. Poë, C. N. Sampson, and R. T. Smith,J. Am. Chem. Soc., 1986,108 5459.

    Article  Google Scholar 

  13. G. Ferraris and G. Gervasio,J. Chem. Soc., Dalton Trans., 1974, 1813.

  14. A. J. Deeming, S. Hasso, and M. Underhill,J. Chem. Soc., Dalton Trans., 1975, 1614.

  15. B. F. G. Johnson, R. Khattar, F. J. Lahoz, J. Lewis, and P. R. Raithby,J. Organomet. Chem., 1987, 319, C51.

    Article  CAS  Google Scholar 

  16. A. A. Koridze, N. M. Astakhova, F. M. Dolgushin, A. I. Yanovsky, Yu. T. Struchkov, and P. V. Petrovskii,Organometallics, 1995,14, 2167.

    Article  CAS  Google Scholar 

  17. A. A. Koridze, A. M. Sheloumov, F. M. Dolgushin, A. I. Yanovsky, Yu. T. Struchkov, and P. V. Petrovskii,Izv. Akad. Nauk, Ser. Khim., 1996, 741 [Russ. Chem. Bull, 1996,45, 702 (Engl. Transl.)].

    Google Scholar 

  18. G. M. Sheldrick,SHELXTL. Version 5, Software Reference Manual, Siemens Industrial Automation, Inc. Madison, 1994.

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    A. A. Koridze, V. I. Zdanovich, V. Yu. Lagunova, M. G. Ezernitskaya, P. V. Petrovskii, F. M. Dolgushin & A. I. Yanovsky

Authors
  1. A. A. Koridze
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. I. Zdanovich
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. Yu. Lagunova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. G. Ezernitskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. P. V. Petrovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. F. M. Dolgushin
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. I. Yanovsky
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1017–1023, May, 1998.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Koridze, A.A., Zdanovich, V.I., Lagunova, V.Y. et al. Unusual rearrangement of the Ru3(μ-CO)2(CO)6{μ3-η1:η1:η4:η4-C4Ph2(CH=CHPh)2} complex containing an open triruthenium framework to the Ru3-triangular cluster Ru3(CO)8{μ3-η1:η1:η4:η2-C4Ph2(CH=CHPh)2}. Reactions of Ru3(CO)8{μ3-η1:η1:η4:η2-C4Ph2(CH=CHPh)2} with PPh3, P(OPri)3, CO, and the crystal structure of Ru3(CO)8(PPh3{μ-η1:η1:η4-C4Ph2(CH=CHPh)2}. Russ Chem Bull 47, 988–994 (1998). https://doi.org/10.1007/BF02498173

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02498173

Key words

Search

Navigation