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Unusual coupling of diynes and CO on an Ru3-cluster: Crystal structure of RU3{μ3-CPhCC(O)C(SiMe3)C(C≡CSiMe3)CCPH}(μ-dppm)(μ-CO)(CO)6

  • Organometallic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

Among several products isolated in the reaction between Ru3(μ3-PhC2C≡CPh)(μ-dppm)(CO)8 and Me3SiCэCCэCSiMe3 was the Ru3{μ3-CPhCC(O)C(SiMe3)C(C≡CSiMe3)CCPh)(μ-ddpm)(CO)7 complex formally obtained by coupling of the two diynes and a CO molecule on the Ru3 framework. Other products were Ru4(μ4-PhC2C≡CPh)(μ≡dppm)(CO)10 and the already known complex Ru3{μ3-PhCCHCC(C6H4}(μ-dppm)(CO)8.

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Authors and Affiliations

  1. Department of Chemistry, University of Adelaide, 5005, Adelaide, South Australia

    M. I. Bruce & N. N. Zaitseva

  2. Department of Chemistry, University of Western Australia, 6907, Nedlands, Western Australia

    B. W. Skelton & A. H. White

Authors
  1. M. I. Bruce
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  2. N. N. Zaitseva
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  3. B. W. Skelton
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  4. A. H. White
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1012–1016, May, 1998.

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Bruce, M.I., Zaitseva, N.N., Skelton, B.W. et al. Unusual coupling of diynes and CO on an Ru3-cluster: Crystal structure of RU3{μ3-CPhCC(O)C(SiMe3)C(C≡CSiMe3)CCPH}(μ-dppm)(μ-CO)(CO)6 . Russ Chem Bull 47, 983–987 (1998). https://doi.org/10.1007/BF02498172

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  • DOI: https://doi.org/10.1007/BF02498172

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