Abstract
The reaction ofcis-Ar2Pt(PPh3)2 (Ar=p-MeC6H4 (1a) and Ar=Ph (1b)) with [60]fullerene in toluene afforded the metal-fullerene complex η2-C60Pt(PPh3)2 (2), which was isolated in the crystalline state. The reductive elimination between C60 and1a or1b also resulted in the formation of biaryls (p-MeC6H4)2 and Ph−Ph. The composition and structure of the compounds were established by1H and31P NMR spectroscopy, electronic absorption spectroscopy, and elemental analysis. The homolytic phosphorylation of2 was additionally studied by the ESR method.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
P. J. Fagan, J. C. Calabrese, and B. Malone,Acc. Chem. Res., 1992,25, 134.
V. V. Bashilov, P. V. Petrovskii, V. I. Sokolov, S. V. Lindeman, I. A. Guzey, and Yu. T. Struchkov,Organometallics, 1993,12, 991.
P. J. Fagan, J. C. Calabrese, and B. Malone,Science, 1991,252, 1160.
V. V. Bashilov, P. V. Petrovskii, and V. I. Sokolov,Izv. Akad. Nauk, Ser. Khim., 1993, 428 [Russ. Chem. Bull., 1993,42, 392 (Engl. Transl.)].
V. V. Bashilov, P. V. Petrovskii, V. I. Sokolov, F. M. Dolgushin, A. I. Yanovskii, and Yu. T. Struchkov,Izv. Akad. Nauk, Ser. Khim., 1996, 1268 [Russ. Chem. Bull., 1996,45, 1207 (Engl. Transl.)].
H. Nagashima, A. Nakaoka, Y. Saito, M. Kato, T. Kawanishi, and K. Itoh,J. Chem. Soc., Chem. Commun., 1992, 377.
H. Nagashima, H. Yamaguchi, Y. Kato, Y. Saito, M. Haga, and K. Itoh,Chem. Lett., 1993, 2153.
H. Nagashima, Y. Kato, H. Yamaguchi, E. Kimura, T. Kawanishi, M. Kato, Y. Saito, M. Haga, and K. Itoh,Chem. Lett., 1994, 1207.
F. J. Brady, D. J. Cardin, and M. Domin,J. Organometal. Chem., 1995,491, 169.
V. V. Bashilov, B. L. Tumanskii, P. V. Petrovskii, and V. I. Sokolov,Izv. Akad. Nauk, Ser. Khim., 1994, 1131 [Russ. Chem. Bull., 1994,43, 1069 (Engl. Transl.)].
J. Chatt and B. L. Shaw,J. Chem. Soc., 1959, 4020.
V. I. Sokolov, V. V. Bashilov, and O. A. Reutov,J. Organometal. Chem., 1975,97, 299.
B. S. Braterman, R. J. Cross, and G. B. Young,J. Chem. Soc., Chem. Commun., 1975, 627.
B. S. Braterman, R. J. Cross, and G. B. Young,J. Chem. Soc., Dalton Trans., 1977, 1892.
C. Eaborn, K. J. Odell, and A. Pidcock,J. Chem. Soc., Dalton Trans., 1978, 357.
H. A. Brune and J. Ertl,Liebigs Ann. Chem., 1980, 928.
B. L. Tumanskii, V. V. Bashilov, S. P. Solodovnikov, N. N. Bubnov, and V. I. Sokolov,Izv. Akad. Nauk, Ser. Khim., 1994, 938 [Russ. Chem. Bull., 1994,43, 884 (Engl. Transl.)].
T. V. Magdesieva, V. V. Bashilov, S. I. Gorel'skii, V. I. Sokolov, and K. P. Butin,Izv. Akad. Nauk, Ser. Khim., 1994, 2153 [Russ. Chem. Bull., 1994,43, 2034 (Engl. Transl.)].
Houben-Weyl,Methoden der organischen Chemie, Band XIII/2b, Metallorganische Verbindungen Hg, Georg Thieme Verlag, Stuttgart, 1974, 329.
Author information
Authors and Affiliations
Additional information
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 575–577, March, 1999.
Rights and permissions
About this article
Cite this article
Bashilov, V.V., Tumanskii, B.L., Petrovskii, P.V. et al. The reaction of diaryl derivatives of bis(triphenylphosphine)platinum(II) with [60]fullerene as a route to the platinum complex η2-C60Pt(PPh3)2 . Russ Chem Bull 48, 570–572 (1999). https://doi.org/10.1007/BF02496181
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02496181