Abstract
Cyclometallation of C60 fullerene with excess AlEt3 in the presence of Cp2ZrCl2 (2 mol % with respect to [Al]) in a toluene solution at 22–23 °C was carried out. The reaction gave 2,3-fullerene-substituted aluminacyclopentanes, whose hydrolysis led to a mixture of hydrogen-containing ethylfullerenes of the type H m C60Et m containing 1 to 12 ethyl groups.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
U. M. Dzhemilev, A. G. Ibragimov, I. R. Ramazanov, and L. M. Khalilov,Izv. Akad. Nauk, Ser. Khim., 1997, 2269 [Russ. Chem. Bull., 1997,46, 2150 (Engl. Transl.)].
H. W. Kroto, J. E. Fischer, and D. E. Cox,The Fullerenes, Pergamon Press, Oxford, U.K., 1993, 318 pp.
W. E. Billups and M. A. Cinfolini,Buckminster Fullerenes, VCH, New York, 1993, 339 pp.
H. W. Kroto, A. W. Allaf, and S. P. Balm,Chem. Rev., 1991,91, 1213.
ACS Symposium Series 481, Eds. G. Hammond and V. J. Kuck,Am. Chem. Soc., Washington, DC, 1992.
V. I. Sokolov and I. V. Stankevich,Usp. Khim., 1993,62, 455 [Russ. Chem. Rev., 1993,62 (Engl. Transl.)].
V. I. Sokolov,Izv. Akad. Nauk, Ser. Khim., 1993, 10 [Russ. Chem. Bull., 1993,42, 1 (Engl. Transl.)].
U. M. Dzhemilev,Tetrahedron, 1995,51, 4333.
U. M. Dzhemilev and A. G. Ibragimov,J. Organomet. Chem., 1994,466, 1.
O. S. Vostrikova, A. G. Ibragimov, R. M. Sultanov, and U. M. Dzhemilev,Metalloorganicheskaya Khimiya, 1992,5, 782 [J. Organomet. Chem. USSR, 1992,5 (Engl. Transl.)].
E. Negishi, D. Y. Kondakov, D. Choueiry, K. Kasai, and T. Takahashi,J. Am. Chem. Soc., 1996,118, 9577.
W. Kaminsky and H. Sinn,Liebigs Ann. Chem., 1975, 424.
W. Kaminsky, J. Kopf, H. Sinn, and H. J. Vollmer,Angew. Chem., Int. Ed. Engl., 1976,15, 629.
Yu. V. Vasil'ev, R. F. Tuktarov, and V. A. Mazunov,Rap. Commun. Mass Spectrom., 1997,11, 757.
Author information
Authors and Affiliations
Additional information
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 572–574, March, 1999.
Rights and permissions
About this article
Cite this article
Dzhemilev, U.M., Ibragimov, A.G., Khafizova, L.O. et al. Synthesis and transformations of metallacycles. Russ Chem Bull 48, 567–569 (1999). https://doi.org/10.1007/BF02496180
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02496180