Abstract
Tris(hydroxymethyl)aminomethane dinitrate benzoate hydronitrate, the first representative of mixed nitric and carboxylic esters of aminopolyatomic alcohols, was obtained by the reaction of a mixture of concentrated HNO3 and Ac2O with 4,4-bis(hydroxymethyl)-2-phenyl-2-oxazoline. X-ray structural analysis demonstrated that the title compound exists in the crystal as two independent molecules.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 505–509, March, 1999.
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Korolev, A.M., Eremenko, L.T., Meshikhina, L.V. et al. Synthesis and study of organic nitrates of the heterofunctional series 3. Synthesis and structure of tris(hydroxymethyl)aminomethane dinitrate benzoate hydronitrate. Russ Chem Bull 48, 501–505 (1999). https://doi.org/10.1007/BF02496169
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DOI: https://doi.org/10.1007/BF02496169