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Interaction of carbonylferrate- and hydridocarbonylferrate anions with Brønstad and Lewis acids

  • Organometallic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

Interaction of carbonylferrate anions Fe n (CO) −1/2− m and hydridocarbonylferrate anions HFe n (CO) −1/− m (wheren=1−4;m=5, 9, 12, 14, respectively) with Brønstad and Lewis acids HX (X=AcO, CF3CO2, HSO4) and RX (R=Alk, Ac, Bn, Bz; X=Cl, Br) is a radical-chain process, occuringvia a one-electron redox-initiation stage, including preliminary activating complex formation. A common approach to the description of the processes of reduction and carbonylation of different organic compounds was suggested. It is based upon the exchange reactions and the interconversions within the coordination spheres of 17-electron coordinatively unsaturated iron carbonyl radical anions, Fe n (CO) −1/− m .

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    Yu. A. Belousov

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya No. 5, pp. 1048–1054, May, 1997.

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Belousov, Y.A. Interaction of carbonylferrate- and hydridocarbonylferrate anions with Brønstad and Lewis acids. Russ Chem Bull 46, 1010–1017 (1997). https://doi.org/10.1007/BF02496136

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  • DOI: https://doi.org/10.1007/BF02496136

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