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Temperature dependence of the ESR line width of C60 − in C60 crystals doped with sodium, potassium, zinc, and indium

  • Physical Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The ESR line width of the C60 − anion in samples of fullerides (Na, K, Zn, and In) with low metal content (0.01%) is ∼0.1 mT at 77 K and ∼1 mT at 300 K. The line shape is fitted better by the Lorentzian function than by the Gaussian function. The spin-lattice relaxation likely makes some contribution to the line width. Time-dependent changes in the ESR spectra were observed: they are related to diffusion of cations to defects of the crystalline lattice.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    S. P. Solodovnikov

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  1. S. P. Solodovnikov
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 669–672, April, 1998.

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Solodovnikov, S.P. Temperature dependence of the ESR line width of C60 − in C60 crystals doped with sodium, potassium, zinc, and indium. Russ Chem Bull 47, 648–651 (1998). https://doi.org/10.1007/BF02495970

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  • DOI: https://doi.org/10.1007/BF02495970

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