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Synthesis of ferrocenylacetylide derivatives of gold-ruthenium and gold-osmium clusters. Crystal structures of M3(AuPPh3)(C≡CFc)(CO)9 (M=Ru or Os; Fc is ferrocenyl)

  • Organometallic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The synthesis and crystal structures of the clusters M3(AuPPh3)(C≡CFc)(CO)9 (M=Ru,3a; or M=Os,3b) are described. Compound3a was synthesized by deprotonation of Ru3H(C≡CFc)(CO)9 under the action of KOH/EtOH followed by treatment of the anionic complex [Ru3(C≡CFc)(CO)9]− with chloro(triphenylphosphine)gold. Compound3b was prepared by the reaction of Os3(CO)10(NCMe)2 with FcC≡CAuPPh3, which was synthesized by the reaction of FcC≡CNa with ClAuPPh3. The pentanuclear cluster Ru4(AuPPh3)(C≡CFc)(CO)12 (4a), which was prepared by the reaction of3a with Ru3(CO)12, was characterized by spectral methods.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    A. M. Sheloumov, A. A. Koridze, F. M. Dolgushin, Z. A. Starikova, M. G. Ezernitskaya & P. V. Petrovskii

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  1. A. M. Sheloumov
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  2. A. A. Koridze
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  3. F. M. Dolgushin
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  4. Z. A. Starikova
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  5. M. G. Ezernitskaya
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  6. P. V. Petrovskii
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Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1295–1299, July, 2000.

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Sheloumov, A.M., Koridze, A.A., Dolgushin, F.M. et al. Synthesis of ferrocenylacetylide derivatives of gold-ruthenium and gold-osmium clusters. Crystal structures of M3(AuPPh3)(C≡CFc)(CO)9 (M=Ru or Os; Fc is ferrocenyl). Russ Chem Bull 49, 1292–1296 (2000). https://doi.org/10.1007/BF02495777

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  • DOI: https://doi.org/10.1007/BF02495777

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