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Crystal and molecular structure of subchrysine (3-O-acetylridentine), a new germacranolide fromArtemisia subchrysolepis

  • Chemistry of Natural Compounds and Bioorganic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

A new sesquiterpenoid lactone was isolated from terrestrial parts ofArtemisia subchrysolepis Filat. and studied by X-ray diffraction analysis and CD spectroscopy. This compound was called subchrysine and identified as (1R,3S,4E,6R,7S)-3-acetoxy-1-hydroxygernmacra-4,10(14), 11(13)-trien-12,6-olide. Pronounced temperature dependence of the1H and13C NMR spectra of subchrysine was observed. The results of conformational analysis of subchrysine by quantum-chemical (PM3) and molecular mechanics (MMX) methods are also presented.

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Authors and Affiliations

  1. Institute of Phytochemistry, Ministry of Science and Academy of Sciences of Kazakhstan Republic, postbox 19 ul. Erdzanova, 470032, Karaganda, Kazakhstan Republic

    A. T. Kulyyasov, S. M. Adekenov & T. S. Seitembetov

  2. Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

    I. Yu. Bagryanskaya, Yu. V. Gatilov, M. M. Shakirov & V. A. Raldugin

Authors
  1. A. T. Kulyyasov
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  2. I. Yu. Bagryanskaya
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  3. Yu. V. Gatilov
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  4. M. M. Shakirov
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  5. V. A. Raldugin
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  6. S. M. Adekenov
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  7. T. S. Seitembetov
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1429–1433, July, 1998.

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Kulyyasov, A.T., Bagryanskaya, I.Y., Gatilov, Y.V. et al. Crystal and molecular structure of subchrysine (3-O-acetylridentine), a new germacranolide fromArtemisia subchrysolepis . Russ Chem Bull 47, 1390–1394 (1998). https://doi.org/10.1007/BF02495573

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  • DOI: https://doi.org/10.1007/BF02495573

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