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Electrochemical hydrogenation of citral

4. Role of the acid component in electrochemical hydrogenation

  • Physical Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The effect of the nature and concentration of the acid component on the yield and ratio of the products of electrocatalytic hydrogenation of citral was studied. The use of weak organic acids (e.g., AcOH) in amounts that are stoichiometric for hydrogenation of conjugated double bonds was shown to be advantageous.

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References

  1. T. Ya. Rubinskaya, L. M. Korotaeva, and V. P. Gul'tyai,Izv. Akad. Nauk, Ser. Khim., 1996, 82 [Russ. Chem. Bull., 1996,45, 74 (Engl. Transl.)].

  2. L. M. Korotaeva, T. Ya. Rubinskaya, and V. P. Gul'tyai,Izv. Akad. Nauk., Ser. Khim., 1993, 1915 [Russ. Chem. Bull., 1993,42, 1830 (Engl. Transl)].

  3. T. Ya. Rubinskaya, L. M. Korotaeva, and V. P. Gul'tyai,Izv. Akad. Nauk, Ser. Khim., 1993, 1919 [Russ. Chem. Bull., 1993,42, 1835 (Engl. Transl.)].

  4. A. N. Nesmeyanov and N. A. Nesmeyanov,Nachala organicheskoi khimii [Basics of Organic Chemistry], Khimiya, Moscow, 1969,1, 316 (in Russian).

    Google Scholar 

  5. A. P. Tomilov, S. G. Mairanovskii, M. Ya. Fioshin, and V. A. Smirnov,Elektrokhimiya organicheskikh soedinenii [Electrochemistry of Organic Compounds], Khimiya, Leningrad, 1968, 68 (in Russian).

    Google Scholar 

  6. B. Paduszek-Kwiateb and M. Kalinowski,Electrochim. Acta., 1984,29, 1439.

    Article  Google Scholar 

  7. S. G. Mairanovskii, M. K. Beisembaeva, and E. A. Mambekaziev,Elektrokhim., 1992,25, 1245 [Sov. Electrochem., 1992,25 (Engl. Transl.)].

    Google Scholar 

  8. G. Horanyi and K. Torkos,J. Electroanal. Chem., 1980,111, 279.

    Article  CAS  Google Scholar 

  9. J.O'M. Bocris and D. A. J. Swinkels,J. Electrochem. Soc., 1964,111, 736.

    Google Scholar 

  10. G. Horanyi and E. M. Rizmayer,J. Electroanal. Chem., 1983,159, 195.

    Article  CAS  Google Scholar 

  11. J. C. Johnston, J. D. Faulkner, L. Maudell, and R. A. Day,J. Org. Chem., 1976,41, 2611.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    L. M. Korotayeva, T. Ya. Rubinskaya & V. P. Gultyai

Authors
  1. L. M. Korotayeva
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  2. T. Ya. Rubinskaya
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  3. V. P. Gultyai
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Additional information

For Communication 3 see Ref. 1.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 480–483, March, 1997.

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Korotayeva, L.M., Rubinskaya, T.Y. & Gultyai, V.P. Electrochemical hydrogenation of citral. Russ Chem Bull 46, 459–462 (1997). https://doi.org/10.1007/BF02495395

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  • DOI: https://doi.org/10.1007/BF02495395

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