Abstract
It is shown that the 1% Pt/CeO2–ZrO2 (1% Pt/CZ) catalytic system allows selective hydrogenation of citral with a 94% conversion and a selectivity towards unsaturated alcohols of 59% at room temperature and atmospheric pressure. The effect of addition of alkali to the reaction mixture on the yield of the target products is studied, and the optimum conditions of the reaction are determined.
Similar content being viewed by others
REFERENCES
S. Clarke, Essential Chemistry for Aromatherapy, 2nd ed. (Churchill, Livingstone, 2008).
S. Gryglewicz, A. Sliwak, J. Cwikta, et al., Can. J. Chem. Eng. 94, 1328 (2016).
E. Bailón-García, F. Carrasco-Marín, and A. F. Pérez-Cadenas, Catal. Commun. 82, 36 (2016).
E. Asedegbega-Nieto, B. Bachiller-Baeza, A. Guerrero-Ruiz, et al., Appl. Catal., A 300, 120 (2006).
J. Court, J. Jablonski, and S. Hamarthibault, Stud. Surf. Sci. Catal. 78, 155 (1993).
S. A. Ananthan, R. Suresh, K. Giribabu, et al., Chem. Sci. Trans. 2 (S1), 111 (2013).
A. Vicente, G. Lafaye, C. Especel, et al., J. Catal. 283, 133 (2011).
P.-F. Qu, J.-G. Chen, Y.-H. Song, et al., Catal. Commun. 68, 105 (2015).
J. P. Stassi, V. I. Rodríguez, M. J. Yañez, et al., Catal. Lett. 147, 1903 (2017).
K. V. Vikanova and E. A. Redina, Russ. J. Phys. Chem. A 92, 2355 (2018).
K. V. Vikanova, E. A. Redina, G. I. Kapustin, N. A. Davshan, and L. M. Kustov, Russ. J. Phys. Chem. A 93, 231 (2019).
E. A. Redina and K. V. Vikanova, Russ. J. Phys. Chem. A 92, 2374 (2018).
J. P. Stassi, V. I. Rodríguez, M. J. Yañez, et al., Catalysts 3, 853 (2013).
V. Satagopan and S. B. Chandalia, J. Chem. Technol. Biotechnol. 59, 257 (1994).
K. C. Tin, N. B. Wong, R. X. Li, et al., J. Mol. Catal. A 137, 113 (1999).
H. J. Jiang, H. B. Jiang, D. M. Zhu, et al., Appl. Catal., A 445–446, 351 (2012).
S. I. Fujita, Y. Sano, B. M. Bhanage, et al., J. Catal. 225, 94 (2004).
U. K. Singh and M. A. Vannice, Appl. Catal., A 213, 1 (2001).
A. B. Merlo, B. F. Machado, V. Vetere, et al., Appl. Catal., A 383, 43 (2010).
Funding
This work was supported by the Russian Science Foundation, grant no. 17-73-20282.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by O. Polyakov
Rights and permissions
About this article
Cite this article
Vikanova, K.V., Redina, E.A. Selective Hydrogenation of Citral on Pt-Containing Catalysts at Room Temperature and Atmospheric Pressure. Russ. J. Phys. Chem. 93, 2566–2569 (2019). https://doi.org/10.1134/S0036024419120318
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024419120318